极性单体的负离子聚合研究进展(Ⅰ)

Progress of Anionic Polymerization of Polar Monomers

本文从单体、单体的精制、引发剂及配位体的种类等方面出发 ,综述了活性负离子聚合法制备各种 (甲基 )丙烯酸烷基酯的均聚物及其与传统非极性单体苯乙烯及丁二烯的嵌段共聚物的研究现状。

This paper deals with the introduction of necessary conditions for anionic homopolymerization of different polar monomers [alkyl(methyl)methacrylates], such as initiators,solvents,ligands as well as reaction temperatures;besides,some block copolymers synthesized from mentioned polar monomers with styrene and butadiene are also introduced, respectively.