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Synthesis, Photophysical and Electrochemical Properties of Amide-Linked Phthalocyanine-Fullerene Dyad

Synthesis, Photophysical and Electrochemical Properties of Amide-Linked Phthalocyanine-Fullerene Dyad
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摘要 metry data. The free energy change for charge separation (AGcs) was estimated to be exothermic with --0.51 eV, which favored the formation of charge-separation state. The PET from ZnPc to C60 in ZnPc-C60 made the dyad exhibit stronger reverse saturable absorption performance compared with C60 and the control sample in the Z-scan experiments, which indicated the synergistic effect of two active moieties in the dyad. metry data. The free energy change for charge separation (AGcs) was estimated to be exothermic with --0.51 eV, which favored the formation of charge-separation state. The PET from ZnPc to C60 in ZnPc-C60 made the dyad exhibit stronger reverse saturable absorption performance compared with C60 and the control sample in the Z-scan experiments, which indicated the synergistic effect of two active moieties in the dyad.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第8期1766-1770,共5页 中国化学(英文版)
关键词 PHTHALOCYANINE FULLERENE electrochemistry photoinduced electron transfer nonlinear optical proper-ties phthalocyanine, fullerene, electrochemistry, photoinduced electron transfer, nonlinear optical proper-ties
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