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Ru-Cu-Ni-CeO_2/HZSM-5催化剂裂解秸秆气化焦油性能研究 被引量:5

Cracking of Tar from Straw Gasification Over Ru-Cu-Ni-CeO_2/HZSM-5 Catalysts
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摘要 采用浸渍法制备Ru-Cu-Ni-CeO2/HZSM-5催化剂,对实验室规模的生物质气化焦油催化裂解的性能进行研究,并与HZSM-5以及Ru-Ni-CeO2/HZSM-5催化剂的性能进行对比.Ru-Cu-Ni-CeO2/HZSM-5催化剂具有高的活性和选择性,主要由于催化剂具有高表面积、适宜的孔分布以及高分散的活性组分. Ru-Cu-Ni-CeO2/HZSM-5 catalysts were made by incipient wetness impregnation. Catalytic performance of the Ru-Cu-Ni-CeO:/HZSM-5 catalysts were studied and compared with performance of HZSM-5 and Ru-Ni- CeO2/HZSM-5 catalyst for syngas cleanup in a laboratory-scale biomass gasifier. It is concluded that Ru-Cu-Ni- Ce02/HZSM-5 catalysts can be applied as effective catalysts for biomass gasification tar removal and syngas conditioning. The excellent activity of the catalysts may be attributed to the utilization of HZSM-5 with high surface area and good pore size distribution and the high dispersion of the active metal components.
出处 《河南科学》 2012年第9期1251-1255,共5页 Henan Science
基金 河南省重点攻关项目(092102310040) 河南省重大科技攻关计划(102101310300)
关键词 生物质气化 秸秆 HZSM-5分子筛 焦油脱除 催化裂解 biomassgasification: straw: HZSM-5 molecular sieve tar removal catalytic cracking
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