摘要
The effect of Co doping on ceria-zirconia mixed oxides was investigated for Co0.1Ce0.6Zr0.3Ox sample prepared by sol-gel method. The Pd-only three-way catalyst （TWC） was obtained by incipient wetness impregnation with 0.5 wt.% Pd loading. The structural and oxygen handling properties were analyzed by X-ray diffraction （XRD）, H2-temperature programmed reduction （H2-TPR） and the dynamic oxygen storage capacity （DOSC）. The introduction of Co into ceria-zirconia lattice strongly modified the mobility of oxygen and enhanced the DOSC performance. Pd-only TWC based on the Co0.1Ce0.6Zr0.3Ox support exhibited superior activity for water-gas shift and steam reforming and ampli- fied amplitude of stoichiometric window.
The effect of Co doping on ceria-zirconia mixed oxides was investigated for Co0.1Ce0.6Zr0.3Ox sample prepared by sol-gel method. The Pd-only three-way catalyst （TWC） was obtained by incipient wetness impregnation with 0.5 wt.% Pd loading. The structural and oxygen handling properties were analyzed by X-ray diffraction （XRD）, H2-temperature programmed reduction （H2-TPR） and the dynamic oxygen storage capacity （DOSC）. The introduction of Co into ceria-zirconia lattice strongly modified the mobility of oxygen and enhanced the DOSC performance. Pd-only TWC based on the Co0.1Ce0.6Zr0.3Ox support exhibited superior activity for water-gas shift and steam reforming and ampli- fied amplitude of stoichiometric window.
基金
Project supported by National High-Tech Research and Development Program of China (2011AA03A405)
the Key Program of Tianjin Natural Science Foundation (09JCZDJC26600)
