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二氰基取代的硫杂冠醚并四硫富瓦烯(TTF)衍生物的合成 被引量：1

Syntheses of dicyano substituted thia crown ether annulated tetrathiafulvalene derivatives
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摘要 在DMF溶液中,采用高度稀释的方法,使二巯基马来二腈的二钠盐和2,3-二(碘乙氧乙氧乙硫基)-6,7-二取代四硫富瓦烯衍生物(化合物3)进行缩合反应,成功地合成了二氰基取代的大环硫杂冠醚并四硫富瓦烯衍生物。用1 HNMR,MS和IR表征了其结构,并用循环伏安法和紫外吸收光谱初步评价了衍生物的电化学性质和光物理性质。 Under high dilution, condensation of disodium maleonitrile 2,3-dithiolate and compound 3 successfully synthesized the dicyano substituted thia crown ether annulated tetrathiafulvalene derivatives. Their structures were characterized by 1HNMR. MS and IR. The electrochemical and photophysical properties were evaluated via cyclic voltamtngrams and UV absorption spectrum.
作者 李东风 侯瑞斌 黄卓
机构地区 长春工业大学化学与生命科学学院
出处 《长春工业大学学报》 CAS 2012年第5期579-582,共4页 Journal of Changchun University of Technology
基金 吉林省科技厅自然科学基金资助项目(20101548)
关键词 高度稀释 四硫富瓦烯 硫杂冠醚 合成 high dilution tetrathiafulvalene thia crown ether synthesis
分类号 O657.33 [理学—分析化学]
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参考文献7

  • 1Otsubo T, Ogura F. Cromled tetrathiafulvalene derivatives[J]. Bull. Chem. Soc. Jpn. , 1985,58 (4) : 1343-1344.
  • 2Hansen T K, Joergensen T, Stein P C, et al. Crown ether derivatives of tetrathiafulvalene[J]. J. Org. Chem. ,1992,57(24) :6403-6409.
  • 3Nieisen M B, Becher J. Two and three-dimensional tetrathiafulvalene macrocycles[J]. Liebigs Ann. Recueil, 1997,18 : 2177-2187.
  • 4Jeppesen J O, Becher J. Pyrrolo-tetrathiafulvalenes and their applications in molecular and supmmolecu- lar chemistry[J]. Eur. J. Org. Chem. ,2003,17: 3245-3266.
  • 5Jrgensen T, HansenK, Becher J. Tetrathiafulvalenes as building-blocks in supramolecular chem- istry[J]. Chem. Soc. Rev. ,1994,23(1):41-51.
  • 6Becher J, Brimert T, Jeppesen J O, et al. Tetrathiafulvaleno-annelated porphyrins [J]. Angew. Chem. lnt. Ed. ,2001,40(13) :2497-2500.
  • 7Hou Rui-bin, Li Bao, Zhong Ke-li, et al. Tetrakis ( tetrathiafulvalene-tetrathiacrown ether ) porphyrazine triads: synthesis photophysieal, and electrochemical properties[J]. Eur. J. Org. Chem., 2012,6 : 1138-1146.

同被引文献8

  • 1Otsubo T, Ogura F. Cromled tetrathiafulva|ene de- rivativesl-J ~. Bull. Chem. Soc. Jpn., 1985, 58 ( 4 ) .. 1343-1344.
  • 2Hansen T K, Joergensen T, Stein P C, et al. Crown ether derivatives of tetrathiafulvalenel-J]. J. Org. Chem., 1992,57(24) :6403-6409.
  • 3Nieisen M B, Becher J. Two-and three-dimensional tetrathiafulvalene macrocycles[J]. Liebigs Ann. Re- cueil, 1997 : 2177-2187.
  • 4Jeppesen J O, Becher J. Pyrrolo-tetrathiafulvalenes and their applications in molecular and supmmolec- ular chemistryl-J]. Eur. J. Org. Chem., 2003, 17.. 3245-3266.
  • 5Jorgensen T, Hansen K, Becher J. Tetrathiaful- valenes as building-blocks in supramolecular chem- istry[J]. Chem. Soc. Revm,1994,23(1):41-51.
  • 6Becher J, Brimert T, Jeppesen J O, et al. Tetrath- iafulvaleno-annelated porphyrinsl-J~. Angew. Chem. Int. Ed. ,2001,40(13) :2497-2500.
  • 7Hou Rui bin, Li Bao, Zhong Ke Li, et al. Tetrakis ( tetrathiafulvalene-tetrathiacrown ether ) por- phyrazine Triads: SyuthesisEJ~. Photophysical andElectrochemical Properties. Eur. J. Org. Chem., 2012(6) ~ 1138-1146.
  • 8Leng Fengshou, Hou Ruibin, Jin Longyi, et al. Synthesis, characterization and electrochemistry of the novel metalloporphyrazines annulated with te- trathiafulvalene having pentoxycarbonyl substitu- ents [J]. Journal of Porphyrins and Phthalocya- nines, 2010,14 .. 110-114.

引证文献1

长春工业大学学报
2012年 第5期

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