电导法测乙酸乙酯皂化反应的动力学数据处理

Accurate calculation to the rate constant of the acetic ether saponification

分别用精确方法和目前各类教材中常用方法处理了电导法测乙酸乙酯皂化反应的动力学数据 .计算结果表明 ,两种方法计算结果相差很大 ,相对误差达4 3 % .

The equations from many books of “Physical Chemistry Experiment” and derived by this paper were used to calculate the rate constant of the acetic ether saponification reaction respectively.There is a large difference between the results calculated by the two equation above mentioned.