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对二甲氨基苯基五唑和对羟基苯基五唑的低温合成与NMR表征 被引量：2

Synthesis and NMR Characterization of p-Dimethylaminophenylpentazole and p-Hydroxyphenylpentazole at Low Temperature
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摘要 分别以对二甲氨基苯胺和对羟基苯胺为原料,在-40℃条件下合成出对二甲氨基苯基五唑(p-DMAPP)和对羟基苯基五唑(p-HPP)。用低温1HNMR、13CNMR、1H-13CHMBC、15NNMR和1H-15NHMBC表征了它们的结构。结果表明,其氢谱和碳谱数据与文献值一致。五唑的N信号分别被指配为:p-DMAPP,N-1(δN-80.0),N-2/5(δN-27.3),N-3/4(δN5.1);对p-HPP,N-1(δN-84.1),N-2/5(δN-28.1),N-3/4(δN4.2)。 p-Dimethylaminophenylpentazole（p-DMAPP） and p-hydroxyphenylpentazole（p-HPP） were synthesized at -40 ℃,using N1,N1-dimethylbenzene-1,4-diamine and 4-aminophenol as starting meaterials, respectively. Their stuctures were characterized by 1H NMR, 13C NMR , 1H-13C HMBC,15N NMR and 1H-15N HMBC at low temperature. The results show that the 1H NMR and 13C NMR data of p-DMAPP and p-HPP are in accordant with the literature values. Nitrogen signals of pentazole are assigned as N-1（δN -80.0）, N-2/5（δN -27.3）, N-3/4（δN 5.1） for p-DMAPP and N-1（δN -84.1）, N-2/5（δN -28.1）, N-3/4（δN 4.2） for p-HPP, respectively. 
作者 徐敏 毕福强 张皋 王民昌 葛忠学 陈智群 许诚
机构地区 西安近代化学研究所
出处 《含能材料》 EI CAS CSCD 北大核心 2012年第5期596-600,共5页 Chinese Journal of Energetic Materials
关键词 有机化学 对二甲胺基苯基五唑 对羟基苯基五唑 合成 核磁共振 organic chemistry p-dimethylaminophenylpentazole p-hydroxyphenylpentazole synthesis NMR
分类号 TQ560.1 [化学工程—炸药化工]
  • 相关文献

参考文献16

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二级参考文献11

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共引文献18

同被引文献27

  • 1张佳利,庞思平,李玉川,于永忠,张慧娟.1-(对二甲氨基苯基)五唑的合成研究[J].含能材料,2006,14(5):355-357. 被引量：19
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二级引证文献9

含能材料
2012年 第5期

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