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Preparation and Electrochemical Properties of Porous Platinum Electrode 被引量：1

Preparation and Electrochemical Properties of Porous Platinum Electrode
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摘要 Porous platinum electrodes were prepared by adding YSZ,as an active material,in platinum paste.Relationship between microstructure and electrochemical performance of O 2(g),Pt/YSZ electrode have been characterized by SEM and cyclic voltammetry.Results showed that the microstructure of platinum electrode is a significant impact on the cyclic voltammetry.With the increase of platinum electrode's porosity,the area of three-phase boundary of O 2(g) /Pt/YSZ was increased.The electrochemical reactivity was also enhanced.These were presented as the increase of current density and cathode voltage in cyclic voltammetry. Porous platinum electrodes were prepared by adding YSZ, as an active material, in platinum paste. Relationship between microstructure and electrochemical performance of O2（g）, Pt/YSZ electrode have been characterized by SEM and cyclic voltammetry. Results showed that the microstructure of platinum electrode is a significant impact on the cyclic voltammetry. With the increase of platinum electrode＇s porosity, the area of three-phase boundary of Oz（g）/Pt/YSZ was increased. The electrochemical reactivity was also enhanced. These were presented as the increase of current density and cathode voltage in cyclic voltammetry.
作者 HE Xin CHEN Boxun CHEN Qiao
机构地区 General Research Institute for Nonferrous Metals
出处 《贵金属》 CAS CSCD 北大核心 2012年第A01期79-84,共6页 Precious Metals
关键词 porous platinum electrode electrochemical performance MICROSTRUCTURE cyclic voltammetry porous platinum electrode electrochemical performance microstructure cyclic voltammetry
分类号 TG146.33 [金属学及工艺—金属材料]
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  • 1孙成文,王梅东,杨芝洲.金属／YSZ多晶陶瓷电极交流阻抗特性[J].无机材料学报,1996,11(1):123-130. 被引量：11
  • 2Moghodam F K, Stevenson D A. Oxygen diffusion and solubility studies in Ag and Pt using AC impedance spectroscopy [ J ]. J Electrochem Soc, 1986,133 (7) : 1329 -1332.
  • 3Wang Dayu , Nowick A S. Diffusion controlled polarization of Pt, Ag and Au electrodes with doped ceria electrolyte [ J ]. J Electrochem Soc, 1981,128 ( 1 ) :55 -63.
  • 4Tsiplakides D, Neophytides S, Vayenas C G. Thermal desorption study of oxygen adsorption on Pt, Ag & Au films deposited on YSZ [ J ]. Ionics, 1997 (3) :201 -208.
  • 5Tsiplakides D, Neophytides S, Vayenas C G. Investigation of the state of the electrochemically generated adsorbed O species on Au films interfaced with Y2O3-doped-ZrO2 [ J]. Ionics, 2001 (7) : 203 -209.
  • 6Mizusaki J, Amano K, Yamauchi S, et al. Electrode reaction at Pt, O2(g)/stabilized zirconia interfaces. Part 1 :Theoretical consideration of reaction model. Part 2 : Electrochemical measurements and analysis[J]. Solid State Ionics,1987,22(4) :313 -330.
  • 7Schwandf C, Weppner W. Kinetics of oxygen, platinum/stabilized zirconia and oxygen, gold/stabilized zirconia electrodes under equilibrium conditions [ J]. J Electrochem Soc, 1997,144 ( 11 ) : 3728 -3738.
  • 8Sasaki K, Hosoda K, Lan T N, et al. Ag-Zr(Sc) O2 cermet cathode for reduced temperature SOFCs [ J ]. Solid State Ionics, 2004, 174( 1 -4) :97 -102.
  • 9Baker R, Guindet J, Kleitz M. Classification criteria for solid oxide fuel cell electrode materials[J]. J Electrochem Soc,1997,144(7) : 2427-2432.
  • 10Badwal S P S, De Bruin H J. Electrode kinetics at the palladium/ ceramic oxide electrolyte interface [ J ]. J Electrochem Soc, 1982, 129(9) :1921 -1928.

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  • 1Zhang J, Deng C, Song J, et a|. MoB-CoCr as alternatives to WC- 12Co for stainless steel protective coating and its corrosion behavior in mohen zinc[J]. Surface & Coatings Technology, 2013, 235:811-818.
  • 2Cao Z, Zhang Q, Li Y. Production and developing trends of gold alloys magnetron sputtering target[J]. Applied Mechanics & Materials, 2013, 331: 492- 496.
  • 3Ma Zhiyuan, Yang Hongying. Optimization of microwave-ultrasound assisted leaching of copper anode slime based on central composite design[C]// Proceedings of the 7th International Symposium on Hydrometallurgy. Victoria: Elsevier, 2014: 813-825.
  • 4Cao Z, Zhang Q, Li Y. Production and developing trends of gold alloys magnetron sputtering target[J]//Applied Mechanics and Materials, Trans Tech Publications. 2013, 331: 492-496.
  • 5唐会毅,吴保安,汪建胜,等.热电偶用强化型铂的制备及性能[J].工业计量,2013(23).20-21.
  • 6Liu W, Chen X, Ye Q, et al. 3-Hydroxycarboplatin, a simple carboplatin derivative endowed with an improved toxicological pro file[J]. Platinum Metals Review, 2012, 56(4): 248-256.
  • 7Yang D L, Zhang X, Yao Y G, et al. Structure versatility of coordination polymers constructed from a semirigid ligand and polynuelear metal clusters[J]. CrystEngComm, 2014, 16(34): 8047-8057.
  • 8Ji C, Ren H, Yang S. Control of manganese dioxide crystallographic structure in the redox reaction between graphene and permanganate ions and their electrochemical performance[J]. Rsc Advanees, 2015, 5(28): 21978-21987.
  • 9卢雯婷,陈敬超,冯晶,于杰.贵金属催化剂的应用研究进展[J].稀有金属材料与工程,2012,41(1):184-188. 被引量：41
  • 10董亭义,万小勇,罗俊锋,高岩,王欣平.高纯Ag变形及退火后的微观组织[J].材料热处理学报,2012,33(1):80-83. 被引量：5

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2012年 第A01期

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