二苯基碘鎓氟硼酸盐引发AGE阳离子光聚合与光交联的研究

Study of Allyl Glycidyl Ether(AGE) Cationic Photopolymerization Initiated by Diphenyliodonium Fluoroborates

用合成的二苯基碘钅翁氟硼酸盐作为光敏引发剂 ,研究了含乙烯基和环氧基两种不同官能基的烯丙基缩水甘油醚 ( AGE)的阳离子光聚合和聚合前后微观结构的变化 ,讨论了其阳离子光聚合的特征和机理 。

With diphenyliodonium fluoroborates as photoinitiators,cationic photopolymerization of allyl glycidyl ether (AGE) was studied.Its characteristic and mechanism of cationic photopolymerization was discussed.