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Polystyrene-supported chloroaluminate ionic liquid as a new heterogeneous Lewis acid catalyst for Knoevenagel condensation 被引量:5

Polystyrene-supported chloroaluminate ionic liquid as a new heterogeneous Lewis acid catalyst for Knoevenagel condensation
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摘要 Non-hygroscopic polystyrene-supported chloroaluminate ionic liquid was prepared from the reaction of Merrifield resin with 1- methylimidazole followed by reaction with aluminum chloride. This Lewis acidic ionic liquid is environmentally friendly heterogeneous catalyst for the Knoevenagel condensation of aromatic and aliphatic aldehydes with ethyl cyanoacetate. The catalyst is sta^le (as a bench top catalyst) and reusable. Non-hygroscopic polystyrene-supported chloroaluminate ionic liquid was prepared from the reaction of Merrifield resin with 1- methylimidazole followed by reaction with aluminum chloride. This Lewis acidic ionic liquid is environmentally friendly heterogeneous catalyst for the Knoevenagel condensation of aromatic and aliphatic aldehydes with ethyl cyanoacetate. The catalyst is sta^le (as a bench top catalyst) and reusable.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2012年第9期1067-1070,共4页 中国化学快报(英文版)
基金 the partial support of this study by the Shahrekord University Research Council
关键词 Ionic liquids Imidazolium chloroaluminate salts Polymer-supported ionic liquids Knoevenagel condensation Ionic liquids Imidazolium chloroaluminate salts Polymer-supported ionic liquids Knoevenagel condensation
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