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介孔材料MCM-41催化吲哚与硝基烯Friedel-Crafts反应的研究 被引量:4

Friedel-Crafts Reaction of Indoles with Nitroalkenes Catalyzed by Mesoporous Material MCM-41
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摘要 用介孔材料MCM-41催化吲哚与β-硝基烯发生Friedel-Crafts反应,成功地合成了天然产物中广泛存在的3-取代吲哚衍生物.该方法具有反应条件温和、操作简单以及环境友好、经济良好等优点,其催化剂也可循环再用. The Frieldel-Crafts reaction of indole with fl-nitrostyrenes catalyzed by MCM-41 was studied. Application of this reaction led to produce 3-substituted indole derivatives being wide present in natural products. The method has several advan- tages of mild reaction, condition handling-up easily, environmental friendly and economic effects. The catalyst can be also recycled.
出处 《有机化学》 SCIE CAS CSCD 北大核心 2012年第10期1970-1974,共5页 Chinese Journal of Organic Chemistry
基金 国家自然科学基金(Nos.20962018 20862015 20562011)资助项目~~
关键词 介孔材料MCM-41 吲哚衍生物 催化 硝基烯烃 Friedel—Crafts反应 mesoporous material MCM-41 indole derivatives catalysis nitroalkenes Friedel-Crafts reaction
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