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Continuous Distillation of Non-ideal Mixtures Through Graphical Methods

Continuous Distillation of Non-ideal Mixtures Through Graphical Methods
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摘要 The current paper deals with the way in which the liquid-vapor equilibrium can be predicted, using the program Microsoft-Excel to obtain the bubble temperatures of twenty different non-ideal mixtures, the location of the azeotrope and the relation of the minimal reflux. The Wilson model was used for the activity coefficient and the cubic equation of state was used for the fugacity coefficient, utilizing the Pitzer correlation for the second virial coefficient.
出处 《Journal of Chemistry and Chemical Engineering》 2012年第7期619-624,共6页 化学与化工(英文版)
关键词 Liquid-vapor equilibrium fugacity coefficient activity coefficient AZEOTROPE distillation. 理想混合物 精馏方法 图形化 立方状态方程 Wilson 第二维里系数 Excel 纸张处理
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参考文献4

  • 1Wilson, Grant M. Vapor-liquid equilibrium. A New expression for the excess free energy of mixing. Journal of American Chemical Society 1964, 86, 127-130.
  • 2Rios, A.; Luis, G. The Thermodynamic Models for the Vapor-Liquid Equilibrium at Low Pressures. Scientia et Technica. 2001, 16, 119-124.
  • 3Smith, J. M.; Van Ness, H. C.; Abbott, M. M. Introduction to Chemical Engineering Thermodynamics; McGraw-Hill, 2003.
  • 4Perry, H. R.; Green, W. D.; Maloney, O. J. Chemical Engineers Handbook; McGraw-Hill: New York, 2004.

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