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Ruthenium Nanoparticles Loaded on Carbon as Effective Catalyst for Highly Selective Hydrogenation of 4,4′-Methylenedianiline 被引量：1

Ruthenium Nanoparticles Loaded on Carbon as Effective Catalyst for Highly Selective Hydrogenation of 4,4′-Methylenedianiline
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摘要 Supported Ru-based catalysts, prepared by a surfactant-stabilized colloidal method, exhibited a good selectivity to bis（4-aminocyclohexyl）methane via the hydrogenation of 4,4′-methylenedianiline. Transmission electron microscopy（TEM） and X-ray diffraction（XRD） characterization showed Ru nanoparticles were well-dispersed on activated carbon, leading to the high activity and selectivity to the product. Supported Ru-based catalysts, prepared by a surfactant-stabilized colloidal method, exhibited a good selectivity to bis（4-aminocyclohexyl）methane via the hydrogenation of 4,4′-methylenedianiline. Transmission electron microscopy（TEM） and X-ray diffraction（XRD） characterization showed Ru nanoparticles were well-dispersed on activated carbon, leading to the high activity and selectivity to the product.
作者 DU Wen-qiang RONG Ze-ming LU Xin-yi WANG Yi-fan LU Lian-hai QU Jing-ping
机构地区 State Key Laboratory of Fine Chemicals
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2012年第5期882-885,共4页 高等学校化学研究（英文版）
基金 Supported by the National High Technology Research and Development Program of China(No.2007AA03Z345)
关键词 Ruthenium-based catalyst 4 4′-Methylenedianiline Hydrogenation Selectivity Ruthenium-based catalyst 4,4′-Methylenedianiline Hydrogenation Selectivity
分类号 TQ113.247 [化学工程—无机化工] TE624.43 [石油与天然气工程—油气加工工程]
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Chemical Research in Chinese Universities
2012年 第5期

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