混合法合成二阶氯化铁-石墨层间化合物的研究

Study on the Synthesis of the Stage-2 FeCl_3-GIC Using the Mixing Method

在前期合成纯一阶 Fe Cl3- GIC工作的基础上 ,设计了混合法合成二阶 Fe Cl3- GIC的实验方案 ,考察了反应温度、C和 Fe Cl3摩尔比 n( C) /n( Fe Cl3)、保温时间对产物阶结构的影响 .首次用混合法合成了纯二阶Fe Cl3- GIC,确立了其最佳反应条件 .

Based upon our previous work on the synthesis of the pure stage 1 FeCl 3 GIC,the experimental program of the synthesis of the pure stage 2 FeCl 3 GIC was designed.The influences of the reaction temperature,the ratio of C/FeCl 3 and the soaked time on the stage structure of the resultant were investigated.And the pure stage 2 FeCl 3 GIC was synthesized using the mixing method firstly while the optimum reaction condition was determined.