二碘化钐和异氰酸苯酯的作用

Reaction of Samarium Diiodide with Phenyl Isocyanate

研究了二碘化钐和异氰酸苯酯的反应 ,分离获得了二碘化钐被氧化的产物 [SmI2 (THF) 5 ][SmI4(THF) 2 ],并经元素分析、红外光谱和X光单晶衍射分析表征。二碘化钐和异硫氰酸苯酯、二硫化碳、二氧化碳反应 ,也均得到同样的钐络合物。

The paper describes the reaction of samarium diiodide with phenyl isocyanate. Samarium diiodide was oxidated to be [SmI 2(THF) 5][SmI 4(THF) 2], characterized by elemental analysis, infrared spectra and single crystal X-ray diffraction analysis. The same product was also isolated when samarium diiodide reacted with phenyl isothiocyanate, carbon disulfide and carbon dioxide.