共聚型氯醇橡胶锂离子聚合物电解质的制备和性能

Preparation and Performances of Polymer Electrolytes Based on the Random Copolymer of Epichlorohydrin and Ethylene Oxide

以共聚型氯醇橡胶(ECO)为基体,通过在基体中溶解不同浓度的LiCF3SO3制备了一系列聚合物电解质.利用差示扫描量热技术(DSC)研究了该体系锂盐浓度对聚合物电解质玻璃化转变温度的影响,用傅里叶变换红外光谱(FTIR)研究了体系内锂盐与聚合物基体的相互作用.结果表明,在相同锂盐浓度下,ECO基聚合物电解质的室温离子电导率比传统的聚环氧乙烷(PEO)基聚合物电解质提高了2个数量级,并且体系电导率在升降温循环测试中没有弛豫现象产生.这是由于ECO基体的非结晶性所致.

A series of polymer electrolytes was prepared by dissolving LiCF3 SO3 at different ratios in the ma- trix of epichlorohydrin elastomers（ECO）. It is found that the conductivity of ECO-LiCF3 SO3 polymer electro- lytes increases by nearly two orders of magnitude compared with that of PEO-LiCF3SO3 polymer electrolytes at ambient temperatures and does not exhibit a conductivity hysteresis in heating and cooling scans. The differen- tial scanning calorimetry （DSC） results show the influence of lithium ion concentration on the glass transition temperature（ Ts） of polymer electrolytes, while the Fourier transform infrared spectra （FFIR） studies demon- strate the interaction between LiCF3SO3 and polymer the lack of conductivity hysteresis for the electrolytes matrix. Both the enhancement of ionic conductivity and could be attributed to the amorphism of ECO.