摘要
The aim of the present work is to remove heavy metals (copper, manganese, and zinc) from industrial wastewater of Baiji refinery using GAC (granular activated carbon). The most important factors affecting adsorption process have been studied, which are granular activated carbon thickness, H, inlet pollutant concentration, Cv, and liquid hourly space velocity, LHSV. All experiments were performed under constant temperature at 25℃ and pH = 7. The experimental apparatus was designed and constructed to enable controlling of the operating conditions. Employing five levels for each of H and LHSV and three levels for Co required 75 runs for each metal. Box-Wilson method was used to reduce the number of experiments to 15 for each metal. The results indicated that copper, manganese, and zinc can be completely removed from wastewater using activated carbon. However, breakthrough time for zinc is low. It is also shown that breakthrough time (TB) and exhaustion time (TE) are inversely proportional with pollutant concentration and LHSV (liquid hour space velocity) while it is directly proportional with the thickness of activated carbon column.