摘要
[目的]分析以茶多酚为亲核剂的木瓜原花青素降解反应产物。[方法]采用液相色谱-电喷雾质谱联用技术(LC-ESI-MS),分析主要降解反应产物。[结果]3个新产物的结构分别推测为(表)儿茶素-(4-8)-(表)没食子儿茶素、(表)儿茶素-(4-8)-(表)没食子儿茶素3-O-没食子酸酯和(表)儿茶素-(4-8)-(表)儿茶素3-O-没食子酸酯。[结论]该研究为木瓜原花青素降解产物进一步在医药品、保健食品、食品添加剂和化妆品等领域上的应用奠定基础。
[Objective] The study aimed to analyze the degradative products that was from the degradative reaction of quince polymeric proanthocyanidins with tea polyphenols as a nucleophile.[Method] LC-ESI-MS technique was adopted to analyze the structures of the main degradative products.[Result] Three new products were deduced as(epi)catechin-(4-8)-(epi)gallocatechin,(epi)catechin-(4-8)-(epi)gallocatechin 3-O-gallate,and(epi)catechin-(4-8)-(epi)catechin 3-O-gallate.[Conclusion] The results could provide scientific basis and support for the further application of the new type antioxidant oligomeric proanthocyanidins in the fields of pharmaceuticals,health foods,food supplement and additives,and costimetics,etc.
出处
《安徽农业科学》
CAS
2012年第31期15095-15096,15099,共3页
Journal of Anhui Agricultural Sciences
基金
云南省教育厅科学研究基金重大专项(ZD2010006)