Advantage of Fluorescence Correlation Spectroscopy for the Study of Polyelectrolytes
Advantage of Fluorescence Correlation Spectroscopy for the Study of Polyelectrolytes
摘要
The advantage of fluorescence correlation spectroscopy to study single chain behavior of polyelectrolytes has been demonstrated by checking the coil-to-globule transition ofpoly 2-vinylpyridine with the change ofpH value in aqueous solution. The ultra-high sensitivity of FCS allows measurement at extreme dilution where the effect of electrostatic interaction between the chains is greatly suppressed. The results exposed first-order conformation tran- sition of P2VP as detected by FCS while inter-chain aggregation occurred in the experiments of dynamic light scat- tering.
The advantage of fluorescence correlation spectroscopy to study single chain behavior of polyelectrolytes has been demonstrated by checking the coil-to-globule transition ofpoly 2-vinylpyridine with the change ofpH value in aqueous solution. The ultra-high sensitivity of FCS allows measurement at extreme dilution where the effect of electrostatic interaction between the chains is greatly suppressed. The results exposed first-order conformation tran- sition of P2VP as detected by FCS while inter-chain aggregation occurred in the experiments of dynamic light scat- tering.
参考文献19
-
1Shea, J. E.; Brooks III, C. L. Annu. Rev Phys. Chem. 2001, 52, 499.
-
2Dobson, C. M.; Sail, A.; Karplus, M. Angew. Chem., Int. Ed. 1998, 37, 868.
-
3Post, C. B.; Zimm, B. H. Biopolymers 1982, 11, 2123.
-
4Bloomfield,, V. A. Curn Opin. Struct. Biol. 1996, 6, 334.
-
5Sedlk, M.J. Chem. Phys. 1996, 105, 10123.
-
6Zhang, Y.; Douglas, J. F.; Ermi, B. D.; Amis, E. J. J. Chem. Phys. 2001, 114, 3299.
-
7Laguecir, A.; Ulrich, S.; Labille, J.; Fatin-Rouge, N.; Stoll, S.; Buffle, J. Eur. Polym. J. 2006, 42, 1135.
-
8Pristinski, D.; Kozlovskaya, V.; Sukhishvilia, S. A. J. Chem. Phys. 2005, 122, 014907.
-
9Wang, S.; Zhao, J.J. Chem. Phys. 2007, 126, 091104.
-
10Wang, S.; Granick, S.; Zhao, J.J. Chem. Phys. 2008, 129, 241102.
-
1梁玉珍,周波,马玲.镉—碘化物—罗丹明B显色体系研究[J].高师理科学刊,2000,20(4):36-38. 被引量：3
-
2李士和,李生泉,张阅军.超高灵敏度显色反应测定痕量锌的研究[J].分析试验室,1991,10(6):23-26. 被引量：8
-
3吴立锋,彭华根,王晓工,刘德山,周其庠.Synthesis and Characterization of Photoresponsive Azo Polyelectrolytes[J].Tsinghua Science and Technology,2001,6(2):173-179.
-
4李士和,李生泉,张阅军.测定痕量铂的超高灵敏度显色反应的研究[J].分析试验室,1992,11(2):35-37. 被引量：10
-
5李文琦,沈荔双.流体室温磷光法测定痕量钛(IV)[J].漳州师范学院学报（自然科学版）,2002,15(4):77-79. 被引量：1
-
6扎热木·萨迪克,都颖,徐静娟,陈洪渊.纳米材料在电化学生物传感器中的应用[J].分析科学学报,2009,25(2):217-222. 被引量：13
-
7李春梅,张艳妙.超高效液相色谱在药物分析中的应用[J].现代养生,2015,0(6):61-61. 被引量：2
-
8多元络合物在光度分析的应用[J].试剂与精细化学品,2007(7):21-21.
-
9产品名称：差示扫描量热仪DSC[J].中国材料科技与设备,2012,8(2):94-94.
-
10发光与发光器件[J].中国光学,2008,3(2):4-5.
