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过渡金属盐改性HZSM-5氧化吸附深度脱除CO_2中的NO 被引量:3

Deep NO removal from CO_2 by oxidation adsorption with HZSM-5 modified by transition-metal salt
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摘要 引言目前人们普遍认为大气中二氧化碳(CO2)浓度的提高导致了温室效应,全球变暖;气候异常,灾难性气候增加。据文献报道[1],人类活动可能产生的3.67万亿吨CO2,现已排放近半。CO2是种宝贵的碳资源,若加以充分回收利用,既能减轻环境污染,同时也能带来经济效益。 Oxidation adsorption of NO was investigated on HZSM-5without and with transition-metal-salt [3.85%(mass)of metal]as adsorbents in a fixed bed.These adsorbents were characterized by SEM,BET,XRD and XRF.The results demonstrated that both HZSM-5and transition-metal-salt-modified HZSM-5can efficiently remove NO from CO2,reducing to a level of less than 0.1×10-6,but for HZSM5exist of CO2will significantly affect NO adsorption.Co/HZSM-5(25)is the best adsorbent with the highest NO adsorption capacity,while the results of NOx-TPD revealed that there is good feasibility of industrial application for Cu/HZSM-5(25),Mn/HZSM-5(25).
出处 《化工学报》 EI CAS CSCD 北大核心 2012年第11期3700-3706,共7页 CIESC Journal
基金 国家火炬计划项目(2007GH560021)~~
关键词 吸附 一氧化氮 二氧化碳 HZSM-5 浸渍法 adsorption nitric oxide carbon dioxide HZSM-5 impregnation
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