摘要
CaZrO3：Sm and CaZrO3：Sm,Gd nanophosphors were synthesized by a facile and efficient sol-gel combustion method. Their structure and optical properties were studied. The photoluminesce （PL） results showed that the phosphor could be efficiently excited by irradiation at wavelengths in the visible light region （350-430nm）. The CaZrO3：Sm nanophosphor exhibited strong yellow-green, orange and red emissions with peak wavelength centered at 565nm （4G5/2→6H5/2）, 601nm （4G5/2→6H7/2） and 645nm （4G5/2→6H9/2）, respectively. The incorporation of Gd3＋ ions could greatly improve the luminescence intensity. The highest emission intensity was observed with 2mol.% Gd3＋ doped CaZrO3：3mol.% Sm powder. The material had potential application in the development of materials for LED’s and other optical devices in the visible region.
CaZrO3：Sm and CaZrO3：Sm,Gd nanophosphors were synthesized by a facile and efficient sol-gel combustion method. Their structure and optical properties were studied. The photoluminesce （PL） results showed that the phosphor could be efficiently excited by irradiation at wavelengths in the visible light region （350-430nm）. The CaZrO3：Sm nanophosphor exhibited strong yellow-green, orange and red emissions with peak wavelength centered at 565nm （4G5/2→6H5/2）, 601nm （4G5/2→6H7/2） and 645nm （4G5/2→6H9/2）, respectively. The incorporation of Gd3＋ ions could greatly improve the luminescence intensity. The highest emission intensity was observed with 2mol.% Gd3＋ doped CaZrO3：3mol.% Sm powder. The material had potential application in the development of materials for LED’s and other optical devices in the visible region.
基金
Project supported by National Natural Science Foundation of China (50972081, 51072098)
the Chinese PLA Medical Science and Technique Foundation (CWS11J243)
Independent Innovation Foundation of Shandong University (2011JC024)
