摘要
以溶胶一凝胶法在Pt/Ti/Si02/Si(111)基底上制备了厚度为30~1110nm的0.7BiFeO3.0.3PbTiO3(0.7BFO-0.3PT)薄膜,研究了薄膜厚度对0.7BFO-0.3PT薄膜的结构与电学性能的影响。结果表明,随着膜厚的增加,晶格常数C与日的比值c/a以及晶粒尺寸都呈现先增大后减小的趋势,但其剩余极化强度及介电常数却均与薄膜厚度呈正比。厚度为180nm的0.7BFO-0.3PT薄膜具有最大的矫顽场(2.99×10^5V/cm)和晶粒均匀度(42nm),同时其品格常数比c/a也达到最大,为1.1299。
0.7BiFeOa-0.3PbTiO3 (0.7BFO-0.3PT) thin films with thicknesses of 30-1 110 nm were fabricated by sol-gel method on Pt/Ti/SiO2/Si(Ill) substrate. The effects of film thickness on structure and electric properties of 0.7BFO-0.3PT films were studied. The results show that with the the increasing of film thickness, the lattice constant ratio c/a increases firstly and then decreases, while the grain size possesses the same changing trend. However, the remanent polarization and permittivity are proportional to the film thickness. The 0.7BFO-0.3PT film with thickness of 180 nm possesses the maximal coercive electric field (2.99Ф×10^5 V/cm) and grain uniformity valuing (42 nm), and the lattice constant ratio c/a reaches the maximum of 1.129 9 simultaneously.
出处
《电子元件与材料》
CAS
CSCD
北大核心
2012年第11期39-42,共4页
Electronic Components And Materials
基金
上海市纳米技术专项资助项目(No.1052nm07300)
关键词
薄膜
结构
电学性能
厚度效应
thin films
structure
electric properties
influence of thickness