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低浓度下强电解质在有机溶剂中的电导率的测定(Ⅰ)LiBr,LiCl和LiNO_3在醇类中(英文) 被引量:2

Measurements of Conductivity for Low Concentration Strong-electrolytes in Organic Solvents (Ⅰ) LiBr, LiCl, and LiNO_3 in Alcohols
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摘要 The conductivities of LiBr, LiCl, and LiNO 3 in methanol, ethanol, 1-propanol, and 2-propanol (with electrolyte concentrations <0.08 mol·L-1 ) were determined at 298.15 K, 313.15 K, and 323.15 K at atmosphere pressure separately by using a conductivity meter. The conductivity data were correlated with Foss-Chen-Justice (FCJ) equation and the limiting molar conductivities were obtained. The mean ionic activity coefficients of the salts in the organic solvents were calculated according to the Debye-Hückel limiting law and Onsager-Falkenhangen equations. The calculated results were compared with those activity coefficients in literature. The conductivities of LiBr, LiCl, and LiNO 3 in methanol, ethanol, 1-propanol, and 2-propanol (with electrolyte concentrations 〈0.08 mol·L-1 ) were determined at 298.15 K, 313.15 K, and 323.15 K at atmosphere pressure separately by using a conductivity meter. The conductivity data were correlated with Foss-Chen-Justice (FCJ) equation and the limiting molar conductivities were obtained. The mean ionic activity coefficients of the salts in the organic solvents were calculated according to the Debye-Hückel limiting law and Onsager-Falkenhangen equations. The calculated results were compared with those activity coefficients in literature.
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第5期1024-1033,共10页 中国化学工程学报(英文版)
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