期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

水溶性壳聚糖/鸡蛋清对仿生碳酸钙晶体形貌的控制 被引量：8

Co-effect of Water-soluble Chitosan and Egg White on the Polymorph and Morphology of Biomimetic Calcium Carbonate
下载PDF
导出
摘要 在水溶性壳聚糖/鸡蛋清的调控下,采用气相扩散法仿生制备出多种形貌的碳酸钙晶体。研究了Ca2+起始浓度、m壳聚糖∶m鸡蛋清质量比对碳酸钙形貌和晶型的影响。采用扫描电子显微镜(SEM)、红外光谱(FT-IR)及X射线衍射(XRD)等测试技术对获得的碳酸钙样品进行表征。XRD及FT-IR结果表明所得碳酸钙包括方解石和球霰石两种晶型,SEM观察表明Ca2+浓度及m壳聚糖∶m鸡蛋清质量比对碳酸钙形貌有重要的调控作用。 Water-soluble chitosan and egg white are used as additives to control the morphology and ploymorph of CaCO3 by a gas diffusion method.The influence of the concentration of Ca2＋ and different ratios of mchitosan：megg white on the polymorph and morphology of CaCO3 crystal are investigated.The samples of the obtained CaCO3 particles were characterized by a sequence of methods including scanning electron microscopy（SEM）,Fourier transform infrared（FT-IR） spectroscopy and powder X-ray diffraction（XRD）.The results showed that the samples were consisted of calcite and vaterite polymorphs,and the concentrations of Ca2＋ and the ratios of mchitosan：megg white had co-effect on the morphology and polymorph of CaCO3 crystals.
作者 郑亮 李兆乾 刘勋 裴重华
机构地区 西南科技大学四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2012年第5期1420-1424,共5页 Journal of Synthetic Crystals
基金 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地开放基金(11zxfk21)
关键词 仿生合成 气相扩散法 水溶性壳聚糖 鸡蛋清 碳酸钙 biomimetic synthesis gas diffusion method water-soluble chitosans egg white calcium carbonate
分类号 O78 [理学—晶体学]
  • 相关文献

参考文献26

  • 1Mann S. Molecular Recognition in Biomineralization [ J]. Nature, 1988,332(10) : 119-124.
  • 2Lowenstam H A, Weiner S. On Biomineralization [ M ]. New York:Oxford University Press, 1989.
  • 3Jackson A P, Vincent J F V, Turner R M. The Mechanical Design of Nacre[J]. Proceedings of the Royal Society of London Series B, 1988,234 ( 1277 ) :415-440.
  • 4Curre J D, Tayl J D. The Mechanical Behavior of Some Molluscan Hard Tissues [ J ]. Journal of Zoology, 1974,173 : 395-406.
  • 5Song F, Soh A K, B ai Y L. Structural and Mechanical Properties of the Organic Matrix Layers of Nacre [ J ]. Bioraaterials ,2003 ,24 (20) :3623- 3631.
  • 6Mann S. Biomineralization: Principles and Concepts in B ioinorganic Materials Chemistry [ M ]. New York: Oxford University Press,2001.
  • 7Elfil H, Roques H. Role of Hydrate Phases of Calcium Carbonate on the Scaling Phenomenon [ J ]. Desalination,2001,137 (1-3 ) :177-186.
  • 8Natoli A, Wiens M, Schrfider H C, et al. Bio-Vaterite Formation by Glycoproteins from Freshwater Pearls [ J ]. Micron,2010,41 (4) :359-366.
  • 9张勇,肖锐,凌立,谢莉萍,任燕,张荣庆.珍珠质水溶性基质蛋白的分离纯化及其对碳酸钙结晶的影响[J].海洋科学,2004,28(1):33-37. 被引量：15
  • 10Gower L A, Tirrell D A. Calcium Carbonate Films and Helices Grown in Solutions of Poly(aspartate) [J]. Journal of Crystal Growth,1998,191 (1-2) :153-160.

二级参考文献27

  • 1[9]Halloran B A,Donachy J E.Characterization of organic matrix macromolecules from the shells of Antarctic scallop,Adamussium colbecki[J].Comp Biochem Physiol,1995,111B: 221-231.
  • 2[10]Almeida M J,Milet C,Peduzzi J,et al.Effect of water-soluble matrix fraction extracted from the nacre of Pinctada maxima on the alkaline phosphatase activity of cultured fibroblasts[J].J Exp Zool,2000,288: 327-334.
  • 3[1]Smith B L,Schaffer T E,Viani M,et al.Molecular mechanistic origin of the toughness of natural adhesives,fibres and composites[J].Nature,1999,399: 761-763.
  • 4[2]Westroek P,Marin F.A marriage of bone and nacre[J].Nature,1998,392: 861-862.
  • 5[3]Addadi L,Weiner S.A pavement of pearl[J].Nature,1997,389: 912-915.
  • 6[4]Watabe N,Wilbur K M.Influence of the organic matrix on crystal type in mollusk[J].Nature,1960,188: 334.
  • 7[5]Falini G,Albeck S,Weiner S,et al.Control of aragonite or calcite polymorphism by mollusk shell macromolecules[J].Science,1996,271: 67-69.
  • 8[6]Belcher A M,Wu X H,Christensen R J,et al.Control of crystal phase switching and orientation by soluble mollusk-shell proteins[J].Nature,1996,381: 56-58.
  • 9[7]Sudo S,Fujikawa T,Nagakura T,et al.Structures of mollusc shell framework proteins[J].Nature,1997,387: 563-564.
  • 10[8]Samata T,Hayashi N,Kono M,et al.A new matrix pro-tein family related to the nacreous layer formation of Pinc-tada fucata[J].FEBS Lett,1999,462: 225-229.

共引文献36

同被引文献120

  • 1吴刚,章守权,李进,王小锋,陈豫.L-赖氨酸对碳酸钙晶体生长的研究[J].南京晓庄学院学报,2009,25(6):33-35. 被引量：2
  • 2张利,李玉宝,杨爱萍,左奕,吕国玉,魏杰.骨组织工程用纳米羟基磷灰石/壳聚糖多孔支架材料的制备及性能表征[J].功能材料,2005,36(2):314-317. 被引量：32
  • 3冯庆玲,侯文涛.碳酸钙生物矿化的体外研究进展[J].清华大学学报（自然科学版）,2006,46(12):2019-2023. 被引量：18
  • 4Yang J, Liu Y H, Wen T, et al. Controlled Mineralization of Calcium Carbonate on the Surface of Nonpolar Organic Fibers [ J ]. Cryst. Growth Des. ,2012,12( 1 ) :29-32.
  • 5Beck R, Andreassen J P. Spherulitic Growth of Calcium Carbonate[J]. Cryst. Growth Des. ,2010,10(7) :2934-2947.
  • 6Price G J, Mahon M F, Shannon J, et al. Composition of Calcium Carbonate Polymorphs Precipitated Using Ultrasound[ J]. Cryst. Growth Des. , 2011,11(1) :39-44.
  • 7Nypelti T, Osterberg M, Laine J. Tailoring Surface Properties of Paper Using Nanosized Proeipitated Calcium Carbonate Particles[ J]. ACS Appl. Mater. InteqCaces ,2011,3 (9) :3725-3731.
  • 8Bassett D C, McKee M D, Barralet J E. The Role of the Air-Liquid Interface in Protein-Mediated Biomineralization of Calcium Carbonate [ J ]. Cryst. Growth Des. ,2011 ,11 (3) :803-810.
  • 9Wolf S E, Leiterer J, Pipich V, et al. Strong Stabilization of Amorphous Calcium Carbonate Emulsion by Ovalbumin : Gaining Insight into the Mechanism of Polymer-Induced Liquid Precursor'Processes[I]. J. Am. Chem. Soc. ,2011,133(32) :12642-12649.
  • 10Picker A, Nuss H, Guenoun P, et al. Polymer Vesicles as Microreactors for Bioinspired Calcium Carbonate Precipitation [ J]. Langmuir ,2011,27 (7) :3213-3218.

引证文献8

二级引证文献30

人工晶体学报
2012年 第5期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部