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Palladium-Catalyzed Suzuki-Miyaura Type Coupling Reaction of Aryl Halides with Triphenylborane-Pyridine

Palladium-Catalyzed Suzuki-Miyaura Type Coupling Reaction of Aryl Halides with Triphenylborane-Pyridine
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摘要 The Suzuki-Miyaura type coupling reaction of aryl halides with triphenylborane-pyridine was described. The reaction can be catalyzed by Pd(OAc)2 (5 mol%) in presence of Cs2CO3 at 50 ℃ or 80 ℃, and functionalized biaryls were obtained in good to excellent yields. This protocol is general and can tolerate a wide range of func- tional groups. The Suzuki-Miyaura type coupling reaction of aryl halides with triphenylborane-pyridine was described. The reaction can be catalyzed by Pd(OAc)2 (5 mol%) in presence of Cs2CO3 at 50 ℃ or 80 ℃, and functionalized biaryls were obtained in good to excellent yields. This protocol is general and can tolerate a wide range of func- tional groups.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第10期2581-2586,共6页 中国化学(英文版)
基金 This work was supported by the Natural Science Foundation of Zhejiang Province (No. Y407081) andthe Research Foundation of Education Department of Zhejiang Province (No. YZ01018492).
关键词 triphenylbroane-pyridine Suzuki-Miyaura coupling aryl halides palladium catalysts triphenylbroane-pyridine, Suzuki-Miyaura coupling, aryl halides, palladium catalysts
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