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Ce-doped LiNi_(1/3)Co_((1/3-x/3))Mn_(1/3)Ce_(x/3)O_2 cathode materials for use in lithium ion batteries 被引量:8

Ce-doped LiNi_(1/3)Co_((1/3-x/3))Mn_(1/3)Ce_(x/3)O_2 cathode materials for use in lithium ion batteries
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摘要 LiNi1/3Co1/3Mn1/3O2 and Ce-doped LiNi1/3Co1/3Mn1/3O2 cathode materials were synthesized by a co-precipitation method and solid phase synthesis and characterized using X-ray diffraction(XRD) and scanning electron microscopy(SEM).The results indicated that the resultant cathode materials with different Ce content all had a good layer structure and high crystallinity.Electrochemical performance testing of the cathode materials showed that the discharge capacity increased with increasing Ce content while the initial reversible capacity attenuation decreased with Ce doping.When the Ce content of the cathode materials is x=0.2,and the current charge and discharge rate is a constant 0.2 C,the discharge capacity maintained 91% of its initial capacity after cycling 50 times. LiNi1/3Co1/3Mn1/3O2 and Ce-doped LiNi1/3Co1/3Mn1/3O2 cathode materials were synthesized by a co-precipitation method and solid phase synthesis and characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicated that the resultant cathode materials with different Ce content all had a good layer structure and high crystallinity. Electrochemical performance testing of the cathode materials showed that the discharge capacity increased with increasing Ce content while the initial reversible capacity attenuation decreased with Ce doping. When the Ce content of the cathode materials is x=0.2, and the current charge and discharge rate is a constant 0.2 C, the discharge capacity maintained 91% of its initial capacity after cycling 50 times.
出处 《Chinese Science Bulletin》 SCIE CAS 2012年第32期4181-4187,共7页
关键词 LINI1 3Co1 3Mn1 3O2 锂离子电池 正极材料 扫描电子显微镜 CE掺杂 阴极材料 掺铈 X-射线衍射 lithium ion batteries, cathode materials, LiNi1/3Co1/3Mn1/3O2
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