摘要
A novel Fe(II) coordination polymer [Fe(L)(trans-1,4-chdc)];~ has been hydrother- mally synthesized by using 1,4-cyclohexanedicarboxylic acid (1,4-H2chdc) and 2-(2-fluoro- phenyl)-lH-imidazo[4,5-f][1,10]phenanthroline (L). Crystallographic data: monoclinic, space group C2/c with a = 14.571(5), b = 32.389(6), c = 10.948(5)A, 18 = 115.186(5)°, V= 4676(3)A3, Z = 8, C27H21FFeN404, Mr = 540.33, De --- 1.535 g/cm3, F(000) = 2224, μ(MoKa) = 0.697 mmI, R = 0.0462 and wR = 0.1110. The two kinds of trans-l,4-chdc ligands link neighboring Fe(II) atoms to yield a two-dimensional layer structure. The π-π interactions between the L ligands of neighboring layers result in a three-dimensional supramolecular architecture. The IR and UV-vis spectra of the compound have been investigated in detail.
A novel Fe(II) coordination polymer [Fe(L)(trans-1,4-chdc)];~ has been hydrother- mally synthesized by using 1,4-cyclohexanedicarboxylic acid (1,4-H2chdc) and 2-(2-fluoro- phenyl)-lH-imidazo[4,5-f][1,10]phenanthroline (L). Crystallographic data: monoclinic, space group C2/c with a = 14.571(5), b = 32.389(6), c = 10.948(5)A, 18 = 115.186(5)°, V= 4676(3)A3, Z = 8, C27H21FFeN404, Mr = 540.33, De --- 1.535 g/cm3, F(000) = 2224, μ(MoKa) = 0.697 mmI, R = 0.0462 and wR = 0.1110. The two kinds of trans-l,4-chdc ligands link neighboring Fe(II) atoms to yield a two-dimensional layer structure. The π-π interactions between the L ligands of neighboring layers result in a three-dimensional supramolecular architecture. The IR and UV-vis spectra of the compound have been investigated in detail.
基金
Supported by the Institute Foundation of Siping City(No.2009011)