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Corrosion Evolution of Reinforcing Steel in Concrete under Dry/Wet Cyclic Conditions Contaminated with Chloride 被引量:11

Corrosion Evolution of Reinforcing Steel in Concrete under Dry/Wet Cyclic Conditions Contaminated with Chloride
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摘要 The corrosion evolution of rebar in concrete was monitored by electrochemical impedance spectroscopy (EIS) under dry/wet alternated accelerated corrosion test. Four stages with different dynamic characteristics were observed during the corrosion evolution. They were passive stage, local corrosion controlled by the charge transfer step, accelerated corrosion controlled by the mass transfer step, and constant rate corrosion controlled by the mass transfer step through a barrier layer. X-ray diffraction (XRD) analysis showed that the corrosion product of rebar in mortar was composed of α-FeOOH, γ-FeOOH and Fe304. The corrosion mechanisms of all four stages were discussed and the corrosion reactions were proposed according to the corrosion product and corrosion evolution characteristics. The corrosion evolution of rebar in concrete was monitored by electrochemical impedance spectroscopy (EIS) under dry/wet alternated accelerated corrosion test. Four stages with different dynamic characteristics were observed during the corrosion evolution. They were passive stage, local corrosion controlled by the charge transfer step, accelerated corrosion controlled by the mass transfer step, and constant rate corrosion controlled by the mass transfer step through a barrier layer. X-ray diffraction (XRD) analysis showed that the corrosion product of rebar in mortar was composed of α-FeOOH, γ-FeOOH and Fe304. The corrosion mechanisms of all four stages were discussed and the corrosion reactions were proposed according to the corrosion product and corrosion evolution characteristics.
出处 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2012年第10期905-912,共8页 材料科学技术(英文版)
关键词 REBAR CONCRETE Electrochemical impedance spectroscopy (EIS) Corrosionevolution Rebar Concrete Electrochemical impedance spectroscopy (EIS) Corrosionevolution
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