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Synthesis and characterization of β-cyclodextrin modified hyperbranched carbosilane as stationary phase for GC 被引量:1

Synthesis and characterization of β-cyclodextrin modified hyperbranched carbosilane as stationary phase for GC
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摘要 A new β-cyclodextrin modified hyperbranched carbosilane stationary phase for gas chromatography was synthesized by substituting the -OH groups of β-cyclodextrin with hyperbranched carbosilane and was coated on the inner wall of fused silica capillary column for gas chromatography. The chromatographic behaviors of the stationary phase were studied. The initial testing results showed that it possessed good separation abilities for several kinds of mixtures, such as benzenes, acrylates, ketones and alkylchlorides. A new β-cyclodextrin modified hyperbranched carbosilane stationary phase for gas chromatography was synthesized by substituting the -OH groups of β-cyclodextrin with hyperbranched carbosilane and was coated on the inner wall of fused silica capillary column for gas chromatography. The chromatographic behaviors of the stationary phase were studied. The initial testing results showed that it possessed good separation abilities for several kinds of mixtures, such as benzenes, acrylates, ketones and alkylchlorides.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2012年第11期1259-1262,共4页 中国化学快报(英文版)
基金 support from the National Natural Science Foundation of China(No.20874057) the Key Natural Science Foundation of Shandong Province of China(No.ZR201 IBZOOl)
关键词 Hyperbranched carbosilane CYCLODEXTRIN Stationary phase Gas chromatography Hyperbranched carbosilane Cyclodextrin Stationary phase Gas chromatography
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