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Friedel-Crafts酰基化催化剂的研究进展 被引量：7

Development of catalysts for Friedel-Crafts acylation
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摘要 Friedel-Crafts酰基化反应在有机合成研究与现代工业生产中有着非常重要的作用,其催化剂主要有Lewis酸、超强酸/盐、离子液体、沸石类以及负载型催化剂。本文分别介绍了上述五类催化剂在F-C酰基化反应中的发展沿革与目前应用情况,分析评价了各类催化剂在该反应中的优缺点,并重点综述了沸石类催化剂和负载型催化剂的研究现状。最后从绿色化学、可持续发展的角度出发,指出沸石类和负载型两类催化剂具有较好的综合催化性能和工业化应用前景,值得进一步研究。 Friedel-Crafts acylation is a very important category of organic synthesis reactions in both academic and industrial fields,and the mostly used catalysts are Lewis acids,super acids and their metal salts,ionic liquids,zeolites and supported catalysts.This paper introduces the development history,current application,and advantages or disadvantages of the aforementioned catalysts,and especially focuses on zeolites and supported catalysts.Zeolites and supported catalysts are worthy of further study,since they have better overall properties and industrial catalysis prospects from the view of green chemistry and sustainable development.
作者 乔兴龙 胡学一 方云
机构地区 江南大学化学与材料工程学院食品胶体与生物技术教育部重点实验室
出处 《化工进展》 EI CAS CSCD 北大核心 2012年第12期2702-2707,共6页 Chemical Industry and Engineering Progress
基金 国家自然科学基金(21276113) 江南大学博士研究生科研究基金(JUDCF09007)项目
关键词 Friedel-Crafts酰基化 LEWIS酸 超强酸 离子液体 沸石 催化剂 负载催化剂 Friedel-Crafts acylation Lewis acid super acid ionic liquid zeolite catalyst supported catalyst
分类号 O643.36 [理学—物理化学]
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参考文献62

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二级参考文献218

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化工进展
2012年 第12期

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