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硅烷改性纤维素材料的制备及对聚丙烯阻燃性能的影响研究 被引量:2

Preparation of Silane-modified Cellulose Material and Its Effect on the Flame Retardancy of Polypropylene
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摘要 通过三乙氧基硅氢改性纤维素合成了一种硅烷改性纤维素材料(SOCL),通过FT-IR、SEM、TG对其进行结构和热性能分析;并把SOCL做碳源与聚磷酸铵(APP)复配成膨胀型阻燃剂(IFR),用于阻燃聚丙烯(PP)。结果表明:硅烷改性纤维素能很好地提高纤维素的热稳定性;与APP复配能有效提高PP的阻燃性。 A kind of silane-modified cellulose material (SOCL) was successfully synthesized through modifying cellulose by triethoxysilane compound. The structure and thermal properties of SOCL were analyzed by FT-IR, SEM and TG; SOCL was used as carbon source to form an intumescent flame retardant (IFR) with the presence of ammonium polyphosphate (APP) for polypropylene (PP). The results show that the thermal stability of cellulose improves by adding the silane, and the flame retardant properties of PP obviously improves with the addition of SOCL/APP.
出处 《塑料科技》 CAS 北大核心 2012年第12期50-54,共5页 Plastics Science and Technology
关键词 聚丙烯 三乙氧基硅烷 纤维素 膨胀阻燃 PP Triethoxysilane Cellulose Intumescent flame retardant
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  • 1Camno G, Costa L, Trossarelli L. Study of the mechanism of intumescence in fire retardant polymers. Part Ⅲ: Effect of urea on the ammonium polyphosphate-pentaerythritol system[J]. Polymer Degradation and Stability, 1984, 7(4): 221-229.
  • 2Camno G, Martnasso G, Costa L. Thermal degradation of pentaerythritol diphosphate, model compound for fire retardant intumescent systems. Part I: Overall thermal degradation[J]. Polymer Degradation and Stability, 1990, 27(3): 285-296.
  • 3p Camno G, Martnasso G, Costa L, et al. Thermal degradation of pentaerythritol diphosphate, model compound for fire retardant intumescent systems. Part Ⅱ: Intumescence step[J].Polymer Degradation and Stability, 1990, 28(1 ): 17-38.
  • 4Bourbigot S, Le Bras M, Delobel R. Carbonization mechanisms resulting from intumescence association with the ammonium polyphosphate-pentaerythritol fire retardant system[J]. Carbon, 1993, 31(8): 1 219-1 230.
  • 5Bourbigot S, Le Bras M, Delobel R. Carbonization mechanisms resulting from intumescence. Part Ⅱ: Association with an ethylene terpolymer and the ammonium polyphosphate-pentaerythritol fire retardant system[J]. Carbon, 1995, 33(3): 283-294.
  • 6Lewin M. Synergism and catalysis in flame retardancy of polymers[J]. Polymers for Advanced Technologies, 2001, 12(3-4): 215-222.
  • 7Bourbigot S, Le Bras M, Delobel R, et al. Zeolites: New synergistic agents for intumescent fire retardant thermoplastic formulations-criteria for the choice of the zeolite[J]. Fire and Materials, 1996, 20(3): 145-154.
  • 8R M Estevao L, Le Bras M, Delobel R, et al. Structure-property relationship in intumescent polymeric formulations containing wastezeolite-based material as a synergistic agent[J]. European Polymer Journal, 2004, 40(7): 1 503-1 513.
  • 9Le Bras M, Bourbigot S, Tallec Y, et al. Synergy in intumescence-application to β-cyclodextrin carbonisation agent in intumescent additives for fire retardant polyethylene formulations[J]. Polymer Degradation and Stability, 1997, 56(1): 11-21.
  • 10Li B. Xu M J. Effect of a nove flame flame Stabil retardancy and therma charring-foaming agent on degradation of intumescent retardant polypropylene[J]. Polymer Degradation and ty, 2006, 91(6): 1 380-1 386.

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  • 1DASH R, CATETO C A, RAGAUSKAS A J. Synthesis of a co-cross-lir~ked nanocomposite hydrogels from poly ( methyl vinyl ether-co-maleic acid ) -polyethylene glycol and nanofibrillated cellulose [ J ]. Cellulose, 2014,21 ( 1 ) : 529 -534.
  • 2VUOTI S, TALJA R, JOHANSSON L S, et al. Solvent impact on esterification and film formation ability ~ff nanofibrillated cellulose [ J ]. Cellulose,2013,20(5) :2359-2370.
  • 3VIRTANEN S, VUOTI S, HEIKKINEN H,et al. High strength modified nanofibrillated cellulose-polyvinyl alcohol films[ J ]. Cellulose,2014,21 (5) :3561-3571.
  • 4NADERI A, LINDSTROM T, SUNDSTROM J. Carboxymethylated nanofibrillated cellulose : Rheological studies [ J ]. Cellulose, 2014,21 ( 3 ) : 1561-1571.
  • 5EYHOLZER C, LOPEZ-SUEVOS F, TINGAUT P, et al. Reinforcing effect of carboxymethylated nanofibrillated cellulose powder on hydroxypropyl cellulose [ J ]. Cellulose,2010,17 (4) :793-802.
  • 6EYHOLZER C,BORDEANU N,LOPEZ-SUEVOS F, et al. Preparation and characterization of water-redispersible nanofibrillated cellulose in powder form [ J ]. Cellulose,2010,17 ( 1 ) : 19-30.
  • 7KALIA S, BOUFI S, CELLI A, et al. Nanofibrillated cellulose: Surface modification and potential applications [ J ]. Colloid and Polymer Science,2014,292( 1 ) :5-31.
  • 8NELSON M L, O' CONNOR R T. Relation of certain infrared bands to cellulose crystallinity and crystal latticed type. Part [. Spectra of lattice types I, II, III and of amorphous cellulose [ J ]. Journal of Applied Polymer Science, 1964,8 ( 3 ) : 1311 - 1324.
  • 9KAPLAN D L. Biopolymers from renewable resources [ M ]. Berlin : Springer, 1998 : 1-417.
  • 10平郑骅,叶匀分,丁雅娣,胡晓华,丁之明.傅里叶红外光谱法研究高分子共混物的相容性[J].复旦学报(自然科学版),1997,36(4):439-444. 被引量:11

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