原子转移自由基聚合在制备新型材料中的应用

Application of Atom Transfer Radical Polymerization (ATRP) in Synthesis of Novel Materials

原子转移自由基聚合(ATRP)技术是一种新型的可控活性聚合技术,可有效地对聚合物的分子结构进行设计,制备出各种不同性能、不同组成、不同功能化的结构确定的聚合物材料。综述了利用ATRP技术在制备有机—无机杂化材料、功能性膜材料、水凝胶材料、液晶材料方面的最新进展,最后对原子转移自由基聚合技术的发展做出了展望。

Atom transfer radical polymerization （ATRP） is one of the new techniques employed in living/controlled radical polymerization. It is effective in the design of molecular structure of polymers. A variety of well defined polymers with different properties, composition and functions can be prepared by ATRP. In this paper, applications and research progress of ATRP in the fields of organic-inorganic hybrid materials, fimctional membrane, and hydrogels liquid crystal materials were introduced, and finally its development trend was prospected.