基于琼脂支撑的液/液界面上AgTCNQ的电化学合成(英文)

Electrochemical Synthesis of Silver-Tetracyanoquinodimethane Nanorods at Agar Supported Water/1,2-Dichloroethane Interface

具有高导电性和独特电学性质的金属有机络合物AgTCNQ是一种重要的电荷转移盐.本文采用琼脂作为胶凝剂构成水|1,2-二氯乙烷液液界面,施加电压时银离子由水相穿过水凝胶进入有机相,与TCNQ-反应生成AgTCNQ纳米棒.结果表明液/液界面电化学方法为合成有机金属功能材料的有效途径.

Silver-tetracyanoquinodimethane （AgTCNQ） is an important charge transfer salt due to its high conductivity and other electronic properties.In this communication,we report the synthesis of AgTCNQ at the liquid/liquid interface.Agar was used as a gelling agent to support water/1,2-dichloroethane （DCE） interface.Silver ions were transferred from the hydrogel into DCE phase,where they combined with TCNQ to form AgTCNQ nanorods.The developed method can provide a new route for synthesis of functional materials based on the electrochemistry at the liquid/liquid interface.