摘要
以三氟甲磺酸(CF3SO3H)为催化剂,1-己烯、1-癸烯、1-十二碳烯为原料进行齐聚反应合成低黏度PAO,考察了催化剂用量、反应温度、反应时间及烯烃原料组成对PAO收率及性能的影响。结果表明:在反应温度为40℃、反应时间为3h、催化剂与原料摩尔比为0.36的条件下,合成PAO的100℃运动黏度为4.83mm2/s、凝点为-30℃、黏度指数为140,PAO收率在70%以上,其性能能够满足高质量的PAO合成润滑油基础油的要求。
Poly-alpha-olefins synthetic oil (PAO) was one of the most widely used synthetic lubri- cants at present. The oligomerization of C6, C10, C12 α-olefins was studied with CF3SO3 H as catalyst. The effects of process conditions including catalyst dosage, feed composition, reaction temperature and reaction time, on the PAO yield and the performance of synthetic lubricant were studied. Results showed that under the conditions of catalyst/feed molar ratio of 0.36, reaction temperature of 40℃ and reaction time of 3 h, PAO with low viscosity (100 ℃ kinematic viscosity of 4.83 mm2/s), low condensa- tion point (--30℃) and high viscosity index (140) was synthesized with a yield of above 70%, and its performance well met the requirements of base oil for high quality PAO synthetic lubricants.
出处
《石油炼制与化工》
CAS
CSCD
北大核心
2012年第12期75-77,共3页
Petroleum Processing and Petrochemicals
基金
辽宁省教育厅资助项目(20060506)
关键词
三氟甲磺酸
混合α-烯烃
齐聚
聚Α-烯烃
低黏度
trifluoromethanesulfonic acid
mixed α-olefins
oligomerization
poly-alpha-olefin
low viscosity