摘要
Diels-Alder反应是一类高选择性、高产率、高可靠性和环境耐受性的反应。从其发现以来,已广泛应用于有机合成化学,成为click化学中的一种类型。近来,在具有特殊结构的高分子合成中,Diels-Alder反应也由于其广泛的实用性与正交性逐渐成为重要的链接手段之一。本文以各类结构高分子的合成作为分类方法,综述Diels-Alder反应在构建这些高分子中的应用。在此基础上,本文展望了Diels-Alder反应在高分子科学中的一些应用前景。发展方法学、应用于特殊结构聚合物的合成、拓宽功能化是相关研究中的关键性问题。
Diels-Alder reaction is a kind of reaction with high selectivity, high productivity, high reliability and condition tolerability. Ever since its discovery, it has been widely used in the organic synthetic chemistry and become a click chemistry. Recently, the Diels-Alder reaction is also gradually becoming an important linking method in the preparation for polymers with well-defined architectures, due to its broad practicability and orthogonality. Based on the classification of polymer architecture, this paper reviews the applications of Diels-Alder reaction in preparing these polymers. Moreover, the paper gives the outlook for further prospect of Diels-Alder reaction in the polymer science. The relative key questions include methodology developments, application in the preparation of polymers with more specialized architectures, and broadening the functional usages.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2012年第12期2342-2351,共10页
Progress in Chemistry
基金
国家自然科学基金项目(No.21174076
51073090
20836004)
国家重点基础研究发展计划(973)项目(No.2009CB930602)资助