三氟甲基侧取代氧、氮、硫杂大环化合物的合成和分子结构

Molecular Structures and Synthesis of oxa - , aza - , thia - Macrocyclic Compounds with Trifluoromethyl Side Groups

合成了四个三氟甲基侧取代氧、氮、硫杂大环化合物，通过对ＩＲ、＾１Ｈ ＮＭＲ、ＭＳ和元素分析作了表征；用ＡＭ１方法计算它们的电子结构，并根据计算结果给出了它们的几何构型。

Four novel oxa - , aza - and thia - marocyclic compounds with trifluoromethyl side group have been synthesized and identified by IR, NMR, MS and elemental analysis. Their electronic structure are calculated using semi - empirical method AMI. On the basis of the calculation their configurations are given.