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Ru(bpy)_3^(2+)在MCM-48中的组装及其发光性质 被引量：4

The Assembly of Tris(bipyridine)ruthenium(Ⅱ) in MCM-48 and Photoluminescent Properties of Assembly Products
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摘要 Tris(bipyridine)ruthenium(Ⅱ)(Ru(bpy) 2+ 3) was incorporated into mesoporous silicate MCM 48. X ray diffraction and emission spectroscopy were used to investigate the products, Ru(bpy) 2+ 3/MCM 48. The emission spectra show that the wavelength of maximum intensity( λ max ) for Ru(bpy) 2+ 3 increases with the increase of Ru(bpy) 2+ 3 loading level in MCM 48. The photoluminescent property of Ru(bpy) 2+ 3/MCM 48 was investigated. It was observed that the wavelength maximum intensity( λ max ) for Ru(bpy) 2+ 3/MCM 48 was red shifted when acetone vapor was introduced. [WT5HZ] Tris(bipyridine)ruthenium(Ⅱ)(Ru(bpy) 2+ 3) was incorporated into mesoporous silicate MCM 48. X ray diffraction and emission spectroscopy were used to investigate the products, Ru(bpy) 2+ 3/MCM 48. The emission spectra show that the wavelength of maximum intensity( λ max ) for Ru(bpy) 2+ 3 increases with the increase of Ru(bpy) 2+ 3 loading level in MCM 48. The photoluminescent property of Ru(bpy) 2+ 3/MCM 48 was investigated. It was observed that the wavelength maximum intensity( λ max ) for Ru(bpy) 2+ 3/MCM 48 was red shifted when acetone vapor was introduced. [WT5HZ]
作者 房铭 张萍 李守贵 王悦 徐如人
机构地区 吉林大学无机合成与制备开放实验室 吉林大学超分子结构与谱学开放实验室
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2000年第7期1016-1017,共2页 Chemical Journal of Chinese Universities
基金 国家自然科学基金! (批准号 :2 97710 13 59790 50 0 6)资助
关键词 Ru(bpy)^2+3 组装 发光性质 MCM-48 Tris(bipyridine)ruthenium(Ⅱ) Mesoporous silicate Assembly Photoluminescent photoluminescent property
分类号 O614.821 [理学—无机化学]
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参考文献10

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同被引文献48

  • 1张慧东,张萍,孙迎辉,叶开其,张晶莹,王悦.喹吖啶酮衍生物/介孔分子筛MCM-41组装体的金属离子传感性能研究[J].高等学校化学学报,2006,27(3):506-509. 被引量：3
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引证文献4

二级引证文献15

高等学校化学学报
2000年 第7期

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