摘要
E,E) 3,7 Dimethyl 2,6 decadiene 1,10 diol(3), a terpenoid diol component of pheromonal secretion of the male queen butterfly, was synthesized stereoselectively from geraniol in seven steps. The key steps were the iodization rearrangement of 2,3 epoxy alcohol 6 and Claisen rearrangement of allyl vinyl ether 8.
E,E) 3,7 Dimethyl 2,6 decadiene 1,10 diol(3), a terpenoid diol component of pheromonal secretion of the male queen butterfly, was synthesized stereoselectively from geraniol in seven steps. The key steps were the iodization rearrangement of 2,3 epoxy alcohol 6 and Claisen rearrangement of allyl vinyl ether 8.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2000年第8期1237-1239,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金! (批准号 :2 9672 0 15 )
关键词
2
3-环氧醇
碘代重排
克莱森重排
合成
二元醇
Epoxy alcohol
Iodization rearrangement
Claisen rearrangement
Synthesis
