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超细粉TiO_2光催化氧化SO_2的研究 被引量:22

Studies on Photocatalytic Oxidation Reaction of SO_2 over TiO_2
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摘要 The influence of the baked temperature for TiO 2 ultrafine particles on the photocatalytic oxidation reaction of SO 2 was investigated. The photocatalytic activity of TiO 2 baked at 320 ℃ is higher than that at other temperatures(480 ℃, 550 ℃). It may be explained by the surface state of TiO 2, increasing the content of surface hydroxyl is helpful to enhance the photocatalytic activity. According to the experimental results, the first order kinetic reaction and the mechanism of the reaction were suggested, also the rate constants and half life time were reported. The influence of the baked temperature for TiO 2 ultrafine particles on the photocatalytic oxidation reaction of SO 2 was investigated. The photocatalytic activity of TiO 2 baked at 320 ℃ is higher than that at other temperatures(480 ℃, 550 ℃). It may be explained by the surface state of TiO 2, increasing the content of surface hydroxyl is helpful to enhance the photocatalytic activity. According to the experimental results, the first order kinetic reaction and the mechanism of the reaction were suggested, also the rate constants and half life time were reported.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2000年第8期1299-1300,共2页 Chemical Journal of Chinese Universities
关键词 光催化氧化 二氧化钛 二氧化硫 大气污染 TiO 2 SO 2 Photocatalytic oxidation reaction
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