Cu_2(bipy)_3(Mo_4O_(14))的水热合成与荧光性质

Hydrothermal synthesis and fluorescence properties of Cu_2(bipy)_3(Mo_4O_(14))

在水热条件下,合成了一种新颖的二维化合物Cu2(bipy)3(Mo4O14)(bipy=4,4′-联吡啶),并通过元素分析和X射线单晶衍射对该化合物进行了表征.结果表明:标题化合物属于三斜晶系,p-1空间群;晶胞参数a=8.166 5(9)nm,b=10.854 3(13)nm,c=11.779 2(13)nm,α=99.460(2)°,β=107.086(2)°,γ=111.386(2)°,V=885.03(17)nm3,Z=2.常温下该化合物表现出黄色的荧光性质.

A novel 2D complex Cu2（bipy）3（Mo4O14）was synthesized under hydrothermal conditions.It was structurally characterized by elemental analyses,X-ray diffraction.The crystal data for this compound are the following：it crastallizes in the triclinic system,space group pi,a=8.166 5（9） nm,b=10.854 3（13） nm,c=11.779 2（13） nm,α=99.460（2）°,β=107.086（2）°,γ=111.386（2）°,V=885.03（17） nm3,Z=2.This compound exhibits yellow emission under ambient temperature.