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Direct Asymmetric Michael Additions of Ketones to Nitroolefins and Chalcones Catalyzed by a Chiral C2-Symmetric Pyrrolidine-based Tetraamine

Direct Asymmetric Michael Additions of Ketones to Nitroolefins and Chalcones Catalyzed by a Chiral C2-Symmetric Pyrrolidine-based Tetraamine
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摘要 C2-Symmetric pyrrolidine-based tetraamine, available from commercially starting materials, showed good cata- lytic activity for asymmetric Michael additions of ketones to nitroalkenes especially to chalcones. The reactions proceeded to give the corresponding products in good yields and in a highly selective manner. C2-Symmetric pyrrolidine-based tetraamine, available from commercially starting materials, showed good cata- lytic activity for asymmetric Michael additions of ketones to nitroalkenes especially to chalcones. The reactions proceeded to give the corresponding products in good yields and in a highly selective manner.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第11期2707-2713,共7页 中国化学(英文版)
关键词 asymmetric catalysis Michael addition tetraamine CHALCONES ENANTIOSELECTIVITY asymmetric catalysis, Michael addition, tetraamine, chalcones, enantioselectivity
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参考文献47

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