叠氮类含能铜(Ⅱ)配合物的合成、结构及感度研究

Synthesis,Crystal Structure and Sensitivity Characterization of Energetic Azide Copper(Ⅱ) Complex

合成了一个叠氮类含能铜配合物Cu(Arg)2(N3)2.3H2O(1)(Arg:L-精氨酸),并用元素分析,红外光谱,单晶X-射线衍射对配合物(1)进行了表征。晶体学数据:单斜晶系,P2(1)/m空间群,a=1.30351(12)nm,b=1.54172(15)nm,c=1.44227(10),α=90.00°,β=122.870(6)°,γ=90.00°,V=2.4344(4)nm3,Z=4,ρcalc=1.501g/cm3,S=1.027,最终偏离因子R1=0.1042,wR2=0.2255,对全部数据R1=0.1414,wR2=0.2422。

A mononuclear energetic complex Cu（Arg）2（N3）2·3H2O（1）（Arg： L-arginine） was prepared and characterized by elemental analysis,IR and single crystal X-ray diffraction analysis.Crystal data： monoclinic,space group P2（1）/m,a = 1.30351（12） nm,b = 1.54172（15） nm,c = 1.44227（10）,α = 90.00°,β = 122.870（6）°,γ= 90.00°,V=2.4344（4） nm 3,Z=4,ρcalc=1.501 g/cm3,S = 1.027,final R indices（I 2σ（I）） R1 = 0.1042,wR2 = 0.2255,for all reflections R1=0.1414,wR2=0.2422.