天然有机物的相对分子质量分布及亲疏水性对微滤膜组合工艺中膜污染的影响

Effect of Relative Molecular Mass Distribution and Hydrophilicity/Hydrophobicity of NOM on Membrane Fouling in MF-combined Process

研究采用混凝沉淀+粉末活性炭吸附+高锰酸钾+浸没式微滤膜的组合工艺对太湖水进行中试试验,通过高效凝胶色谱(HPSEC-UV-TOC)和三维荧光(3DEEM)的测定方法,着重考察有机物的相对分子质量(Mr)分布和亲疏水性对膜不可逆污染的影响.凝胶色谱分析表明:预处理可几乎完全去除大分子有机物(Mr>10×103),但仅能去除部分的中等分子(10×103>Mr>1×103)和小分子(Mr<1×103)有机物.研究发现化学清洗水中的有机物相对分子质量多为中等分子和小分子,说明导致膜不可逆污染的主要是中等分子和小分子有机物.此外,洗膜水中强疏和中性亲水组分含量远高于弱疏和极性亲水,说明强疏和中性亲水组分是不可逆污染的主要物质.三维荧光分析表明,芳香族蛋白质和溶解性微生物产物是造成膜不可逆污染的主要污染物.

This study investigated the reversible and irreversible foulants in a submerged microfiltration（MF） with pretreatments（coagulation/powdered activated carbon（PAC）/potassium permanganate） in a pilot scale treatment of water from Taihu Lake.The study focused on the effect of relative molecular mass（Mr） distribution and hydrophilicity/hydrophobicity on membrane fouling using high performance size-exclusion chromatography（HPSEC） with UV and TOC detectors and three dimension fluorescence excitation-emission matrix（3DEEM）.HPSEC analyses showed that pretreatments could almost completely remove the macro molecules（Mr10×103）,but only eliminate part of medium（10×103Mr1×103） and micro molecules（Mr1×103）.A majority of medium and micro molecules were found in chemical cleaning solutions,indicating that medium and micro molecules were the main foulants that contributed to irreversible membrane fouling.In addition,it was also found that the content of strong hydrophobic acids（SHA） and neutral hydrophilic（Neut） fractions in chemical solutions were far higher than that of weakly hydrophobic acids（WHA） and charged hydrophilic（Char）,which suggested that both organic fractions were responsible for irreversible fouling.3DEEM fluorescence demonstrated that aromatic proteins and soluble microbial products were the main contributors to irreversible membrane fouling.