期刊文献+

水性环氧固化剂的制备及其涂膜性能研究 被引量:3

Preparation of Waterborne Epoxy Curing Agent and Properties of Its Film
下载PDF
导出
摘要 采用丙烯酸丁酯改性三乙烯四胺(TETA),以环氧树脂E-51为封端剂,制备水性环氧固化剂。研究表明:在反应温度为70℃、反应时间为3 h、n(三乙烯四胺加成物)∶n(环氧树脂)为2∶1时,制备的水性环氧固化剂性能优良,与环氧乳液配制的涂料的涂膜具有硬度高,附着力好、流平性好、光泽高等优点。 A novel waterborne epoxy curing agent was prepared by n -butyl acrylate, triethylene tetra- mine (TETA) anti liquid epoxy resin E-51 as a termination agent of the adduct. The results showed that when the reaction temperature was 70 ℃ for 3 h and the molar ratio of adduct to epoxy was 2: 1, the curing agent could provide excellent properties. The film showed good properties such as hardness, adhesion, leveling, gloss.
出处 《涂料工业》 CAS CSCD 北大核心 2013年第1期19-22,共4页 Paint & Coatings Industry
关键词 水性环氧固化剂 改性 三乙烯四胺 waterborne epoxy curing agent modification triethylene tetramine
  • 相关文献

参考文献8

二级参考文献11

  • 1潘祖仁.高分子化学[M].北京:化学工业出版社,1988.
  • 2从树枫,等.聚氨酯涂料.北京:化学工业出版社,2003:57-185
  • 3EGUSA S,SASAKI T,HAGIWARA M.Water-dispersible graft copolymer mixtures prepared by electron irradiationⅠ.Polymerization behavior[J].J Appl Polym Sci,1987(34):2163-2176.
  • 4HIRENDRA K P,LOUISVILLE KY.Aqueous epoxy resin acrylic resin coating compositions containg also phenoxy,novolac and resole resin combination:US,4963602[P].1990.
  • 5MATTHEHEWS JAMES F,SOMMERFELD EUGEE G.Water-borne coating composition made from epoxy resin,polymeric acid and tertiary amine:US,4247439[P].1981-01-27.
  • 6WOO,J T K TOMAN A.Water-based epoxy-acrylic graft copolymer[J].Prog Org Coat,1993(21):371-385.
  • 7姚元斌,裘祖南.胶体与表面化学[M].天津:南开大学出版社,1988.216.
  • 8GUIRONG PAN,LIMIN WU,ZHUQING ZHANG,et al.Synthesis and characterization of epoxy-acrylat composite latex[J].J Appl Polym Sci,2002(83):1736-1743.
  • 9MCGILL - R, HUMPAGE M. Prolonging the life of reinfowed concrete structures by surface treatments [ M ]. Protection of Concrete, 1990: 191 - 200.
  • 10程琪,耿桂生,罗锋,吴三余,赵大林.LSW-2 型海工钢筋混凝土结构防腐蚀涂料的研究与应用[J].水运工程,1998(2):15-18. 被引量:4

共引文献34

同被引文献25

引证文献3

二级引证文献15

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部