摘要
An unprecedented single-stranded polynorbornene with the pendant group containing benzenedicarboxaldehyde and a long alkyl chain（12） was synthesized by ring-open metathesis polymerization（ROMP） of the corresponding monomer（11）,which was obtained via the esterification of two crucial intermediates,namely,2-hexadecyloxy-5-hydroxymethyl-1,3-benzenedicarboxaldehyde（7,obtained via 6 steps） and 4-（4-aza-tricyclo[5.2.1.0 2.6 ]-dec-8en-4-yl）benzoic acid（10）.The target compound and all the intermediates were characterized by infrared（IR）,1 H NMR and high resolution mass spectroscopy（HRMS） analysis.
An unprecedented single-stranded polynorbornene with the pendant group containing benzenedicarboxaldehyde and a long alkyl chain（12） was synthesized by ring-open metathesis polymerization（ROMP） of the corresponding monomer（11）,which was obtained via the esterification of two crucial intermediates,namely,2-hexadecyloxy-5-hydroxymethyl-1,3-benzenedicarboxaldehyde（7,obtained via 6 steps） and 4-（4-aza-tricyclo[5.2.1.0 2.6 ]-dec-8en-4-yl）benzoic acid（10）.The target compound and all the intermediates were characterized by infrared（IR）,1 H NMR and high resolution mass spectroscopy（HRMS） analysis.
基金
Supported by the National Natural Science Foundation of China(No.20902002)
the Natural Science Foundation of Anhui Province,China(No.10040606Q04)
