期刊文献+

Characterizations and Photocatalytic Activities of Nanocrystalline MTiO_3 (M=Sr, Pb, Co) Prepared via a General Self-propagating Combustion Method 被引量:1

Characterizations and Photocatalytic Activities of Nanocrystalline MTiO_3 (M=Sr, Pb, Co) Prepared via a General Self-propagating Combustion Method
下载PDF
导出
摘要 Nanocrystalline MTiO3 (M = St, Pb, Co) were prepared by a general self-pro- pagating combustion method. The samples were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2 adsorption and UV-vis diffuse reflectance spectra (DRS). The photocatalytic activity of MTiO3 (M = Sr, Pb, Co) was evaluated by the photocatalytic degradation of methyl orange (MO). MTiO3 (M = Sr, Pb, Co) having the same core element showed distinctly different photocatalytic activity due to the different coordinating atoms. Factors affecting the photocatalytic activity of MTiO3 (M = Sr, Pb, Co) were discussed. It was suggested that the structures of TiO6 octahedra and the electronic property were the predominant factors of the photocatalytic behavior for MTiO3 (M = Sr, Pb, Co). Nanocrystalline MTiO3 (M = St, Pb, Co) were prepared by a general self-pro- pagating combustion method. The samples were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2 adsorption and UV-vis diffuse reflectance spectra (DRS). The photocatalytic activity of MTiO3 (M = Sr, Pb, Co) was evaluated by the photocatalytic degradation of methyl orange (MO). MTiO3 (M = Sr, Pb, Co) having the same core element showed distinctly different photocatalytic activity due to the different coordinating atoms. Factors affecting the photocatalytic activity of MTiO3 (M = Sr, Pb, Co) were discussed. It was suggested that the structures of TiO6 octahedra and the electronic property were the predominant factors of the photocatalytic behavior for MTiO3 (M = Sr, Pb, Co).
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第12期1852-1860,共9页 结构化学(英文)
基金 financially supported by the Educational Commission of Fujian Province(No. JB11005) Fund for Fostering Excellent Young Key Teachers of Fujian Normal University (fjsdjk2012067)
关键词 MTiO3 (M = Sr PB Co) PHOTOCATALYTIC self-propagating combustion MTiO3 (M = Sr, Pb, Co), photocatalytic, self-propagating combustion
  • 相关文献

参考文献30

  • 1Fan, X. X.; Wang, Y.; Chen, X, Y.; Gao, L.; Luo, W, J.; Yuan, Y. P.; Li. Z. S.; Yu, T,; Zhu, J. H,; Zou, Z. G. Facile method to synthesize mesoporous multimetal oxides (ATiO3, A = Sr, Ba) with large specific surface areas and crystalline pore walls, Chem. Mater. 2010, 22, 1276-1278.
  • 2Xian, T.; Yang, H.; Dai, J. F.; Wei, Z. Q.; Ma, J. Y.; Feng, W. J. Photocatalytic properties of SrTiO~ nanoparticles prepared by a polyacrylamide gel route. Mater. Lett. 2011, 65, 3254-3257.
  • 3Lin, X. P.; Huang, F. Q.; Wang, W. D.; Wang, Y. M.; Xia, Y. J.; Shi, J. L. Photocatalytic activities of MzSb_~O7 (M = Ca, Sr) for degrading methyl orange. Appl. Catal. A: Gen. 2006, 313,218-223.
  • 4Lin, X.; Wu, J.; Lv, X.; Shah, Z.; Wang, W.; Huang, F. Novel antimonate photocatalysts MSb206 (M = Ca, Sr and Ba): a correlation between packing factor and photocatalytic activity. Phys. Chem. Chem. Ph~'s. 2009 11, 10047-10052.
  • 5Bi, J. H.; Wu, L.; Zhang, Y. F.; Li, Z. H.; Li, J. Q.; Fu, X. Z. Solvothem~al preparation, electronic structure and photocatalytic properties of PbMoO4 and SrMoO4. Appl. Catal. B: Environ. Z009, 91,135-143.
  • 6Sato, J.; Saito, N.; Nishiyama, H.; lnoue, Y. Photocatalytic activity for water decomposition of indates with octahedrally coordinated d10 configuration. 1. influences of preparation conditions on activity d. Phys. Chem. B 2003, 107, 7965-7969.
  • 7Sato, J.; Nishiyama, H.; lnoue, Y, Photocatalytic activity for water decomposition of indates with octahedrally coordinated dl0 configuration. II. roles of geometric and elecltronic structures. J. Phys. Chem. B 2003, 107, 7970-7975,.
  • 8Liu, S. Z.; Wang, T. X.; Yang, L. Y. Low temperature preparation of nanocrystalline SrTiO3 and BaTiO3 from alkaline earth nitrates and TiO2 nanocrystals. Powder TechnoL 2011, 212, 378-381.
  • 9Miyauchi, M. Thin films of single-crystalline SrTiO3 nanorod arrays and their surface wettability conversion. J. Phys. Chem. C 2007, 111, 12440-12445.
  • 10Li, Y.; Gao, X. P.; Li, G. R.; Pan, G. L.; Yah, T. Y.; Zhu, H. Y. Titanate nanofiber reactivity: fabrication of MTiO3 (M = Ca, Sr, and Ba) perovskite oxides. J. Phys. Chem. C 2009, 113, 4386-4394.

同被引文献1

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部