摘要
采用水热法合成了一个新的双核镉的配位聚合物[Cd(dpa)(bipy)(H2O)]2(H2dpa=2,2'-联苯酸,bipy=2,2'-联吡啶).对其进行了元素分析、红外光谱表征和X-射线单晶衍射测定.该配合物属于单斜晶系,空间群P21/c,晶体学数据为:a=11.2524(13),b=9.5480(11),c=20.675(2),β=104.637(2)o,V=2149.2(4)3,C48H36Cd2N4O10,Mr=1053.61,Dc=1.628g/cm3,μ(MoKα)=1.055mm-1,F(000)=1056,Z=2,R1=0.0317,wR2=0.0807.
A new dinuclear Cadmium coordination polymer [ Cd (dpa) (bipy) ( H2O) ] 2 ( H2 dpa = 2,2'- diphenic acid, bipy = 2,2'- bipyridine) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum and single -crystal X -ray diffraction. The complex crystallizes in monoclinic, space group P2 1/c with a = 11. 2524 (13), b = 9. 5480 ( 11 ), c = 20. 675 (2)A, β = 104. 637 (2)°, V =2149. 2(4)A3,C48H36Cd2N4O10, Mr = 1053. 61, Dc =1.628g/cm3, μ(MoKα) = 1.055mm-1 , F (000) = 1056, Z =2, R1 =0.0317, wR2 =0.0807.
出处
《通化师范学院学报》
2012年第12期23-24,57,共3页
Journal of Tonghua Normal University
基金
吉林省教育厅科学技术研究项目(吉教科合字[2011]第459号)
关键词
水热合成
晶体结构
镉(Ⅱ)配合物
hydrothermal synthesis
crystal structure
Cd (II) complex