期刊文献+

组合发泡剂对聚苯乙烯发泡行为的影响研究 被引量:3

Effects of Compound Foaming Agents on Foaming Behavior of Polystyrene
下载PDF
导出
摘要 采用物理发泡剂和化学发泡剂的组合发泡剂对聚苯乙烯(PS)在串联挤出发泡机组中进行连续挤出发泡,探讨了不同含量发泡剂和不同发泡温度对PS发泡行为的影响。通过真密度测定仪和扫描电子显微镜对发泡制品的密度、发泡倍率和泡孔形态进行测试。研究结果表明,采用组合复合发泡剂后,PS发泡制品的泡孔密度明显提高,发泡倍率增加,泡体结构优于单独使用物理发泡剂或化学发泡剂的发泡制品。在发泡温度为120℃,CO2注气量为5 mL/min,化学发泡剂用量为3份,SiO2用量为1份时,样品具有最佳泡孔形态,发泡倍率为18.42,泡孔密度为3.53×106个/cm3。 Foaming extrusion of polystyrene(PS) was processed using the combination of physical and chemical foaming agents on the single-single screw extruder tandem extrusion line.The effects of foaming agents and foaming temperature on the foaming behaviors of PS were discussed.The foam density and foam morphology of PS were tested by densitometer and scanning electron microscopy.The results show that the cell density and expansion ratio of samples increase, and the cell morphology of PS improves effectively using compound foaming agents, compared with the foaming products produced by physical or chemical foaming agent alone. From the experiment data, when the forming temperature is 120 ℃, CO2 volume flow rate is 5 mL/min, chemical agent content is 3%, and SiO2 content is 1%, PS form has optimal cell morphology, whose expansion ratio and cell density of sample is 18.42 and 3.53 × 106 cells / cm3, respectively.
出处 《工程塑料应用》 CAS CSCD 北大核心 2013年第1期91-95,共5页 Engineering Plastics Application
关键词 挤出发泡 聚苯乙烯 组合发泡剂 泡沫材料 泡孔形态 extrusion foaming polystyrene compound foaming agent foaming materials cell morphology
  • 相关文献

参考文献17

  • 1王向东,王勇,郭鑫齐,等.挤塑聚苯乙烯泡沫塑料[M].北京:化学工业出版社,2011.
  • 2王向东,周洪福,刘伟,刘本刚.组合发泡剂对聚丙烯发泡行为的影响研究[J].工程塑料应用,2012,40(7):76-80. 被引量:3
  • 3Sato Y, Iketani T.Solubility and adsorption of high pressure carbon dioxide to poly(styrene)[J].Fluid Phase Equilibria, 1998,144 (1-2):181-189.
  • 4Shankland I R.CFC alternatives for thermal insulation foams [J]. International Journal of Refrigeration, 1990,13 (2): 113-121.
  • 5Molina M J, Rowland F S.Stratospheric sink for chl0rofluo-romethanes:chlorine atom catalysed destruction of ozone [J].Nature, 1974,249:810-812.
  • 6Kumar V, Vanderwel M, Weller J, et al.Experimental characterization of the tensile behavior of microcelluar polycarbonate foams [J].Journal of Engineering Materials and Technology, 1994,116(4):439-445.
  • 7Tsivintzelis I, Angelopoulou A G, Panayiotou C.Foaming of polymers with supercritical CO2:An experimental and theoretical study [J].Polymer, 2007,48(20):5 928-5 939.
  • 8Tsivintzelis I, Pavlidou E, Panayiotou C.Biodegradable polymer foams prepared with supercritical CO2-thanol mixtures as blowing agents [J].The Journal of Supercritical Fluids, 2007,42(2):265-272.
  • 9Han X M, Koelling K W, Tomasko D L, et al.Continuous microcellular polystyrene foam extrusion with supercritical CO2 [J]. Polymer Engineering and Science, 2002,42(11):2 094--2106.
  • 10Tomasko D L, Burley A, Feng Lu, et al.Development of CO2 for polymer foam applications[J].The Journal of Supercritical Fluids, 2009,47(3):493-499.

二级参考文献48

  • 1王向东,刘本刚,张玉霞,杜中杰,励杭泉.挤出发泡聚丙烯研究[J].中国塑料,2005,19(11):74-77. 被引量:16
  • 2刘本刚,王向东,张玉霞,许国志,陈士宏,杜中杰,叶志殷.线形聚丙烯/长链支化聚丙烯共混物的结晶行为研究[J].中国塑料,2006,20(6):45-50. 被引量:6
  • 3James G B. The Elements of Expansion of Thermoplastics Part Ⅱ[J]. Journal of Cellular Plastics, 1979,14:341- 345.
  • 4Saeed D, Park C B, Mark T K. Processing and Characterization of Microcellular Foamed High-density Polyethylene/Isotactic Polypropylene Blends[J]. Polymer Engineering & Science, 1996,36(7): 1205-1215.
  • 5Park C B,Cheung L K, Seung W S. The Effect of Talc on Cell Nucleation in Extrusion Foam Processing of Polypropylene with CO2 and Isopentane[J]. Cellular Polymers, 1998, 17(4) :221-251.
  • 6Naguib H E, Wang J, Park C B, et al. Effect of Recycling on the Rheological Properties and Foaming Behaviors of Branched Polypropylene[J]. Cellular Polymers, 2003, 22( 1 ):1-22.
  • 7Colton J S, Suh N P. The Nucleation of Microcellular Thermoplastic Foam with Additives: Part Ⅰ: Theoretical Considerations [J].Polymer Engineering & Science, 1987,27: 485-492.
  • 8Colton J S, Suh N P. The Nucleation of Microcellular Thermoplastic Foam with Additives. Part Ⅱ: Experimental Results and Discussion[J]. Polymer Engineering &Science, 1987,27: 493-499.
  • 9Park C B,Burgun S, Bruker M, et al. Noise and vibration confer- ence: Novel acoustical polyolefin foams [ C I//SAE Tech Paper, 2001,01 - 1 556.
  • 10Agarwal P K, Mehta A K. Foamable PP Polymer: US,6174930 [P]. 2001-01-06.

共引文献16

同被引文献102

引证文献3

二级引证文献22

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部