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Different products in the reaction of the alcohols with cyclic and acyclic 1,3-dicarbonyl compounds:K_5CoW_(12)O_(40) as an electron transfer nano catalyst

Different products in the reaction of the alcohols with cyclic and acyclic 1,3-dicarbonyl compounds:K_5CoW_(12)O_(40) as an electron transfer nano catalyst
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摘要 K5CoW12O40 was used as a highly effective catalyst for the benzylation of 1,3-dicarbonyl compounds, β-Keto enol ethers were obtained when cyclic 1,3-dicarbonyl compounds used in this conditions instead of linear ones. The present methodology offers a practical, simple, mild, environmentally friendly, and time-saving method for etherification. Very low loading of catalyst, ease of workup, ease of handling, and reusability of catalyst are other advantages of this catalyst. K5CoW12O40 was used as a highly effective catalyst for the benzylation of 1,3-dicarbonyl compounds, β-Keto enol ethers were obtained when cyclic 1,3-dicarbonyl compounds used in this conditions instead of linear ones. The present methodology offers a practical, simple, mild, environmentally friendly, and time-saving method for etherification. Very low loading of catalyst, ease of workup, ease of handling, and reusability of catalyst are other advantages of this catalyst.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2012年第12期1363-1366,共4页 中国化学快报(英文版)
基金 the Razi University Research Council for support of this work
关键词 BENZYLATION ETHERIFICATION β-Keto enol ethers Nano catalyst POLYOXOMETALATE Benzylation Etherification β-Keto enol ethers Nano catalyst Polyoxometalate
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