六苯基苯衍生物的合成及其应用

Synthesis and Applications of Hexaphenylbenzene Derivatives

六苯基苯衍生物是一类具有独特三维结构的化合物。它可被认为是苯环的6个氢原子均被苯基所取代而成。由于外围6个苯环的空间位阻效应,构成了所谓螺旋桨型的空间结构。基于其独特的刚性立体结构、高的对称性以及其电荷环形离域等特点,六苯基苯衍生物在晶体工程、多孔聚合物、有机电子材料以及骨架材料等领域都受到了极大的关注。本文综述了近年来六苯基苯衍生物的合成及在上述领域中的应用。

With rigid and propeller-like structure, as well as toro derivatives （HPBs） have been of considerable interest for a wide variety porous polymers, organic electronic materials, and other scaffold materi applications of hexaphenylbenzene derivatives in these fields are reviewed. idal of als. delocalization, hexaphenylbenzene applications in crystal engineering, In this paper, the synthesis and